ECIV 350 TEST QUESTIONS AND ANSWERS, Exams of Advanced Education

ECIV 350 TEST QUESTIONS AND ANSWERS

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ECIV 350 TEST QUESTIONS AND ANSWERS
(Lecture 3-5) A water contains two nitrogen species. The concentration of NH3 is 30
mg/L NH3, and the concentration of NO3 - is 5 mg/L NO3 - . What is the total nitrogen
concentration in units of mg N/L? - Answer -25.8 mg N/L
(Lecture 3-5) What pH is required to reduce a high concentration of dissolved Mg2+ to
43 mg/L? Ksp for the following reaction is 10-11.16. Mg(OH)2(s) Mg2+ + 2OH Ksp = 10-
11.16 - Answer -Ph=9.79
(Lecture 3-5) How long will it take the carbon monoxide (CO) concentration in a room to
decrease by 99% after the source of CO is removed and the windows are opened?
Assume the first-order rate constant for CO removal (due to dilution by incoming clean
air) is 1.2/hr. No chemical reaction is occurring. - Answer -2.69
(Hw#1) 3-1 from Textbook. How many grams of NaCl would you need to add to a 1 L
water sample (pH = 7) so the ionic strength equaled 0.1M? - Answer -5.8g
What percentage of total ammonia (i.e., NH3 + NH4 + ) is present as NH3 at pH 7? pKa
for NH4 = 9.3. NH4 + NH3 + H+ - Answer -05%
(Hw#2) 4-6 from Textbook. Poorly treated municipal wastewater is discharged to a
stream. The river flow rate upstream of the discharge point is Qu/s = 8.7 m3 /s. The
discharge occurs at a flow of Qd = 0.9 m3 /s and has a BOD concentration of 50.0
mg/L. Assuming that the upstream BOD concentration is negligible. (a) What is the BOD
concentration just downstream of the discharge point? (b) If the stream has a cross-
sectional area of 10 m2 , what would the BOD concentration be 50 km downstream?
(BOD is removed with a first-order decay rate constant equal to 0.20/day.) - Answer -a)
Cd=4.7 mg/L
V=0.96 m/s
θ=0.6 days
b)Cl=4.20mg/L
(Hw#2) 4-10 from Textbook. In the winter, a stream flows at 10 m3 /s and receives
discharge from a pipe that contains road runoff. The pipe has a flow of 5 m3 /s. The
stream's chloride concentration just upstream of the pipe's discharge is 12 mg/L, and
the runoff pipe's discharge has a chloride concentration of 40 mg/L. Chloride is a
conservative substance. (a) Does wintertime salt usage on the road elevate the
downstream chloride concentration above 20 mg/L? (b) What is the maximum daily
mass of chloride (metric tons/day) that can be discharged through the road runoff pipe
without exceeding the water quality standard? - Answer -a) 21.33 mg/L
b) 16.0 tons/day
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ECIV 350 TEST QUESTIONS AND ANSWERS

(Lecture 3-5) A water contains two nitrogen species. The concentration of NH3 is 30 mg/L NH3, and the concentration of NO3 - is 5 mg/L NO3 -. What is the total nitrogen concentration in units of mg N/L? - Answer - 25.8 mg N/L (Lecture 3-5) What pH is required to reduce a high concentration of dissolved Mg2+ to 43 mg/L? Ksp for the following reaction is 10-11.16. Mg(OH)2(s) Mg2+ + 2OH Ksp = 10- 11.16 - Answer - Ph=9. (Lecture 3-5) How long will it take the carbon monoxide (CO) concentration in a room to decrease by 99% after the source of CO is removed and the windows are opened? Assume the first-order rate constant for CO removal (due to dilution by incoming clean air) is 1.2/hr. No chemical reaction is occurring. - Answer - 2. (Hw#1) 3-1 from Textbook. How many grams of NaCl would you need to add to a 1 L water sample (pH = 7) so the ionic strength equaled 0.1M? - Answer - 5.8g What percentage of total ammonia (i.e., NH3 + NH4 + ) is present as NH3 at pH 7? pKa for NH4 = 9.3. NH4 + NH3 + H+ - Answer - 05% (Hw#2) 4-6 from Textbook. Poorly treated municipal wastewater is discharged to a stream. The river flow rate upstream of the discharge point is Qu/s = 8.7 m3 /s. The discharge occurs at a flow of Qd = 0.9 m3 /s and has a BOD concentration of 50. mg/L. Assuming that the upstream BOD concentration is negligible. (a) What is the BOD concentration just downstream of the discharge point? (b) If the stream has a cross- sectional area of 10 m2 , what would the BOD concentration be 50 km downstream? (BOD is removed with a first-order decay rate constant equal to 0.20/day.) - Answer - a) Cd=4.7 mg/L V=0.96 m/s θ=0.6 days b)Cl=4.20mg/L (Hw#2) 4-10 from Textbook. In the winter, a stream flows at 10 m3 /s and receives discharge from a pipe that contains road runoff. The pipe has a flow of 5 m3 /s. The stream's chloride concentration just upstream of the pipe's discharge is 12 mg/L, and the runoff pipe's discharge has a chloride concentration of 40 mg/L. Chloride is a conservative substance. (a) Does wintertime salt usage on the road elevate the downstream chloride concentration above 20 mg/L? (b) What is the maximum daily mass of chloride (metric tons/day) that can be discharged through the road runoff pipe without exceeding the water quality standard? - Answer - a) 21.33 mg/L b) 16.0 tons/day

4 - 16 from Textbook. A 1.0 × 106 gallon reactor is used in a sewage-treatment plant. The influent biochemical oxygen demand (BOD) concentration is 100 mg/L, the effluent BOD concentration is 25 mg/L, and the flow rate through the reactor is 500 gal/min. (a) What is the first-order rate constant for decay of BOD in the reactor? Assume that the reactor can be modeled as a comply mixed flow reactor (CMFR). Report your answer in units of per hour. (b) Assume that the reactor should be modeled as a plug flow reactor (PFR) with first-order decay, not as a CMFR. In that case, what must the first-order decay rate constant be within the PFR reactor? (c) It has been determined that the outlet concentration is too high, so the residence time in the reactor must be doubled. Assuming all other variables remain constant, what must be the volume of the new CMFR? - Answer - a) 0.090/hour b) K=0.042/hr c)2.0x10^6 gallons A pond is used to treat a dilute municipal wastewater before the liquid is discharged into a river. The inflow to the pond has a flow rate of Q = 200 m3 /min and a BOD concentration of Cin = 50 mg/L. The volume of the pond is 20,000 m3. The purpose of the pond is to allow time for the decay of BOD to occur before discharge into the environment. BOD decays in the pond with a first-order rate constant equal to 0.015/min. What is the BOD concentration at the outflow of the pond, in units of mg/L? - Answer - Cout= 20 mg/L A chemical degrades in a flow-balanced, steady-state CMFR according to first order reaction kinetics. The influent concentration of the chemical is 10 mg/L and the effluent concentration is 2 mg/L. Water is being treated at a rate of 29 m3 /min. The volume of the tank is 580 m3. What is the rate constant? - Answer - k=0.2min^- 1 An owl eats frogs as a delicacy, and his intake of frogs is directly dependent on how many frogs are available. There are 200 frogs in the pond, and the rate constant is 0.1/day. How many frogs are left at the end of 10 days? - Answer - 73 frogs remain (Lecture 6-7) (4.2 from textbook) A pipe from a municipal wastewater treatment plant discharges 1.0 m3/s of poorly treated effluent containing 5.0 mg/L of phosphorus compounds (reported as mg P/L) into a river with an upstream flow rate of 25 m3/s and a background phosphorus concentration of 0.010 mg P/L. What is the resulting concentration of phosphorus (in mg/L) in the river just downstream of the plant flow? - Answer - 0.20mg/L (Lecture 6-7) (4.3 from Textbook) The completely mixed flow reactor (CMFR) shown in Figure 4.1 is used to treat an industrial wastewater, using a reaction that destroys the pollutant according to first-order kinetics, with k = 0.216/day. The reactor volume is 500 m3, the volumetric flow rate of the single inlet and exit is 50 m3/day, and the inlet pollutant concentration is 100 mg/L. What is the outlet concentration after treatment?1. Determine the volume required for a PFR to obtain the same degree of pollutant reduction as the CMFR in Example 4.3. Assume that the flow rate and first-order decay rate constant are unchanged (Q = 50 m3/day, and k = 0.216/day). Calculate the

the concentrations of HOCl and OCl? What percent of the HOCl is dissociated? Assume the temperature is 25 o C. HOCl ↔ H+ + OCl- , pKa = 7.54 - Answer - (Exam 1) A wastewater with an ultimate CBOD of 508 mg O2/L and a k of 0.1/day is discharged to a river at a rate of 1 m3 /s. Assuming instantaneous mixing after discharge, the ultimate CBOD of the river water after it has received the wastewater is 52.6 mg O2/L. The river has a flow rate (Q) equal to 9 m3 /s and a background ultimate CBOD of 2 mg O2/L upstream of the wastewater discharge. Calculate the ultimate CBOD (Lo) and CBOD5 (y5) in the river 100 km downstream of the point of discharge. The river has a width (W) of 20 m and a depth (H) of 5 m. - Answer - 16.5 mg/L O 6.49 mg/L O (Lectures 11-15) (Ref Ex 8.2 from Textbook) A conventional mechanical mixing stirred tank is used for rapid mixing in a water treatment plant with a flow rate of 100 x 106 L/day. The water temperature is 10oC. Determine the tank volume and power requirement (kW). - Answer - 69m^ 73 kW (HW #4) 8-16 from Textbook. Calculate the settling velocity of a 100 μm diameter particle with a specific gravity of 2.4 in 10o C water. - Answer - 21 m/h .45< (HW #4) A 10 x 106 L/d raw water source is to be softened to reduce the hardness. The mineral analysis of the raw water is given below. The average raw water temperature and pH were found to be 10 o C and pH 7.0, respectively. Using the given information, determine the total, carbonate, and noncarbonate hardness present in the raw water - Answer - TH: 212. CH: 195 mg/L as CaCO NCH: 17.5 mg/L as CaCO (Lecture 1 6 - 18) A municipal wastewater treatment plant treats an average flow of 12,000 m3/day and a peak hourly flow of 30,000 m3/day. Two circular clarifiers are to be designed, using a depth of 4 meters and overflow rate of 40 m3/m2-day. Calculate the area, diameter, volume, and detention time required for each clarifier. - Answer - 919m^ D: 13.8 m DTime: 0.99h (Lectures 16-18) (Ref Ex 9.4 from Textbook) Given the following information, determine the design volume of the aeration basin and the aeration period of the wastewater for an activated-sludge treatment process: population = 150,000; flow rate is 33.75 X 106 L/day (equals 225 L/person-day); and influent BOD5 concentration is 444 mg/L (note this is high-strength wastewater). Assume that the regulatory agency enforces an effluent standard of BOD5 = 20 mg/L and a suspended-solids standard of 20 mg/L in the treated wastewater. A wastewater sample is collected from the biological reactor

and is found to contain of suspended-solids concentration of 4,300 mg/L. The concentration of suspended solids in the plant influent is 200 mg/L, and that which leaves the primary clarifier is 100 mg/L. The microorganisms in the activated-sludge process can convert 100 g BOD5 into 55 g biomass. They have a maximum growth rate of 0.1/day a - Answer - 0.12 day=3h (Lectures 16-18) (Ref 9.5 from Textbook) Using data provided from Example 9.4, how many kg of primary and secondary dry solids need to be processed daily from the treatment plant? - Answer - 3,376 kg primary solids/day 4,486 kg secondary solids/day (Lectures 16-18) (Ref 9.6 from Textbook) Determine the F/M ratio (in units of lb. BOD5/lb.MLSS-day), using data provided from Example 9.4 - Answer - .58 lb BOD5/Lb MLSS-day

  1. 9-14 from Textbook. You are provided the following information about a municipal wastewater treatment plant. This plant uses the traditional activated-sludge process. Assume the microorganisms are 55 percent efficient at converting food to biomass, the organisms have a first-order death rate constant of 0.05/day, and the microbes reach half of their maximum growth rate when the BOD5 concentration is 10 mg/L. There are 150,000 people in the community (their wastewater production is 225 L/day-capita, 0. kg BOD5/capita-day). The effluent standard is BOD5 = 20 mg/L and TSS = 20 mg/L. Suspended solids were measured as 4,300 mg/L in a wastewater sample obtained from the biological reactor, 15,000 mg/L in the secondary sludge, 200 mg/L in the plant influent, and 100 mg/L in the primary clarifier effluent. SRT is equal to 4 days. (a) What is the design volume of the aeration basin (m3 )? (b) What is the plant's aeration - Answer - a. 33.75x10^6 L/day b. 0.12 day=2.9h c. 4,515 Kg/day d. if Qw is increased the SRT will decrease e. 0.97 lb BOD/ lb MLVSS-day f. mean cell residence time equals sludge age equals solid retention time =4 days If the F/M ratio is 0.33 lb. BOD5/lb. MLSS-day, estimate the hydraulic retention time of the aeration basins. Assume that the BOD5 is 150 mg/L measured after primary treatment and the concentration of total suspended solids existing the aeration basin is 3,300 mg/L? - Answer - 7.26/day 3.3h 9 - 12 from Textbook. Assume a plant flow of 12,000 m3 /day. Determine the actual detention time observed in the field of two circular settling tanks with depth 3.5 m that was designed to have an overflow rate not exceeding 60 m3 /m2 - day and a detention time of at least 2 hour. - Answer - 42 m^3/m^2-day A bench scale plug flow thermal oxidizer incinerator is being evaluated to operate at a temperature of 225oC and have a gas residence time of 0.3 s. If the pollutant (diethyl