Understanding Electromagnetic Radiation: Wave-Particle Duality, Slides of Chemical Principles

An in-depth exploration of electromagnetic radiation, discussing its nature as a form of energy with both electric and magnetic components. It covers the concepts of wavelength, frequency, and the relationship between them, as well as the photoelectric effect and the wave-particle duality of light. Students will gain a solid understanding of the properties and behavior of electromagnetic radiation.

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Uploaded on 01/31/2014

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Electromagnetic Radiation
Outline
The nature of electromagnetic radiation.
Light as energy.
The workfunction of metals.
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Download Understanding Electromagnetic Radiation: Wave-Particle Duality and more Slides Chemical Principles in PDF only on Docsity!

Electromagnetic Radiation

• Outline

  • The nature of electromagnetic radiation.– Light as energy.– The workfunction of metals.

Electromagnetic Radiation

• Electromagnetic radiation or “light” is a

form of energy.

• Characterized by:

–Wavelength (

–Amplitude (A)

• Has both electric (E) and magnetic (H)

components.

Electromagnetic Radiation (cont.)•

Wavelength (

): The distance between two

consecutive peaks in the wave.

Increasing Wavelength

1

2

3

Unit: length (m)

Electromagnetic Radiation (cont.)•

Frequency (

): The number of waves (or cycles)

that pass a given point in space per second.

Decreasing Frequency

1

2

3

Units: 1/time (1/sec)

Electromagnetic Radiation (cont.)•

We classify electromagnetic radiation bywavelength.

Visible radiation takes up only a small part of theelectromagnetic spectrum.

What statement is true when comparing red lightto blue light?

A. Red light travels at a greater speed than blue light.B. Blue light travels at greater speed than red light.C. The wavelength of blue light is longer.D. The wavelength of red light is longer.

Light as Energy (cont.)

• Planck’s experiments on light emitted from

a solid heated to “incandescence”.

As body is heated, intensity

increases, and peak wavelengthshifts to smaller wavelengths.Can “classical” physicsreproduce this observation?

Light as Energy (cont.)

Comparison of experiment to the “classical”prediction:

Classical prediction isfor significantly higherintensity as smallerwavelengths than whatis observed.

“The Ultraviolet Catastrophe”

Light as Energy (cont.)

In general the relationship between frequency and“photon” energy is

E

photon

= h

  • Example: What is the energy of a 500 nm photon?

= c/

= (3x

8

m/s)/(5.0 x 10

m)

= 6 x 10

14

1/s

E = h

=(6.626 x 10

J.s)(6 x 10

14

1/s) = 4 x 10

J

Which type of photon will have the largest energy?

A. UltravioletB. X-Ray

C. MicrowaveD. Visible

The Photoelectric Effect

  • Shine light on a metal and observe

electrons that are released.

  • Find that one needs a minimum

amount of photon energy to seeelectrons (“

o

  • Also find that for

o

number of electrons increases linearly with light intensity.

metal

The Photoelectric Effect (cont.)

The Photoelectric Effect (cont.)

  • For Na with

= 4.4 x 10

J,

what wavelength corresponds to

o

m

e

2

h

photon

h

= 4.4 x 10

J

hc

= 4.4 x 10

J

 

hc

x

10

19

J

x

10

34

J

.

s

3

x

10

(^8)

m

/

s

x

10

19

J

= 4.52 x 10

m = 452 nm

0

0 Frequency (

)

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In a workfunction experiment using 300 nm light, theelectrons ejected from Potassium (K) have a greatervelocity that those ejected from Sodium (Na).Therefore:

A.

Na

K

B.

K

Na

C.

K

Na

D.

K

metal