Understanding Clebsch-Gordon Coefficients & Transformation Matrices for Angular Momentum, Assignments of Quantum Mechanics

An in-depth explanation of adding angular momenta and the role of clebsch-gordon coefficients in transforming product states into eigenstates of total angular momentum. It covers the mathematical derivation of important relations, the procedure for constructing total angular momentum eigenstates, and a sample calculation.

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PHY662, Spring 2004
Examples for Adding Angular Momentum
6th February 2004
The ideas you need for the homework have been presented in lecture and/or in Shankar’s
text, but here are a couple of clarifying comments. All of this is standard material,
which can also be found in the texts on QM on reserve in the library.
Looked at mathematically, Clebsch-Gordon coefficients represent the transformation
matrix from the product representation to a representation where the states are eigen-
vectors of J2and Jz.
Important relations
Let |jmibe an eigenstate of J2and Jz, with J=j¯h(i.e., J2=j(j+ 1)¯h2) and Jz=
m¯h. Now note that J+J+JJ+= (Jx+iJy)(JxiJy) + (JxiJy)(Jx+iJy) =
2J2
x+ 2J2
y, as the cross terms all cancel. But in the commuttor, the squares cancel and
the cross terms add up, so [J+, J] = 2(iJyJxiJxJy) = 2i¯h[Jx, Jy] = hJz, so
J+J=JJ++ hJz. Then
JzJ|jmi=Jz(JxiJy)|jmi
= (JzJxiJzJy)|jmi
= (JxJz(i¯hJy)iJyJzi(i¯hJx))|jmi
=J(Jz¯h)|jmi
=J(m1)¯h|jmi
= [(m1)¯h]J|jmi,
and
J2J|jmi= (J2
z+J2
x+J2
y)(JxiJy)|jmi
= (J2
z+1
2(J+J+JJ+))J|jmi
={JzJ(Jz¯h) + 1
2(JJ+J+ hJzJ+JJJ++ hJJz)}|jmi
={J(Jz¯h)2+1
2J(J+J+ hJ(Jz¯h) + JJ++ hJz)}|jmi
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PHY662, Spring 2004

Examples for Adding Angular Momentum

6th February 2004

The ideas you need for the homework have been presented in lecture and/or in Shankar’s text, but here are a couple of clarifying comments. All of this is standard material, which can also be found in the texts on QM on reserve in the library.

Looked at mathematically, Clebsch-Gordon coefficients represent the transformation matrix from the product representation to a representation where the states are eigen- vectors of J^2 and Jz_._

Important relations

Let |jm〉 be an eigenstate of J^2 and Jz , with J = j¯h (i.e., J^2 = j(j + 1)¯h^2 ) and Jz = m¯h. Now note that J+J− + J−J+ = (Jx + iJy )(Jx − iJy ) + (Jx − iJy )(Jx + iJy ) = 2 J x^2 + 2J y^2 , as the cross terms all cancel. But in the commuttor, the squares cancel and the cross terms add up, so [J+, J−] = 2(iJy Jx − iJxJy ) = − 2 i¯h[Jx, Jy ] = 2¯hJz , so J+J− = J−J+ + 2¯hJz. Then

Jz J−|jm〉 = Jz (Jx − iJy )|jm〉 = (Jz Jx − iJz Jy )|jm〉 = (JxJz − (−i¯hJy ) − iJy Jz − i(−i¯hJx))|jm〉 = J−(Jz − ¯h)|jm〉 = J−(m − 1)¯h|jm〉 = [(m − 1)¯h]J−|jm〉 ,

and

J^2 J−|jm〉 = (J z^2 + J x^2 + J y^2 )(Jx − iJy )|jm〉

= (J z^2 +

(J+J− + J−J+))J−|jm〉

= {Jz J−(Jz − ¯h) +

(J−J+J− + 2¯hJz J− + J−J−J+ + 2¯hJ−Jz )}|jm〉

= {J−(Jz − ¯h)^2 +

J−(J+J− + 2¯hJ−(Jz − ¯h) + J−J+ + 2¯hJz )}|jm〉

= J−{J z^2 − 2¯hJz + ¯h^2 +

(J+J− + J−J+) − ¯h^2 + 2¯hJz }|jm〉

= J−J^2 |jm〉 = j(j + 1)¯h^2 J−|jm〉

which implies that J−|jm〉 = α|j, m − 1 〉, as it has the proper eigenvalues for J^2 and Jz. What is the normalization constant α? This can be determined only up to a phase (which is set to 1 here), by computing the norm of J−|jm〉 (note that the adjoint state to J−|jm〉 is 〈jm|J+), with J−|jm〉 =

j(j + 1) − m(m − 1)|j, m − 1 〉, by the notes from Feb. 03 (class 07).

Computing Clebsch-Gordon coefficients

We add together two angular momenta (for example, spins of two particles, or the spin of a particle and its angular momentum). What we want to do is find the states with definite Jtot^ and definite J ztot , where “tot” refers to the total angular momentum operators, with (Jtot)^2 = ( J~ 1 I 2 + I 1 J~ 2 )^2 and J ztot = (J 1 ,z I 2 + I 1 J 2 ,z ), where the subscript refers to which angular momentum is being operated on. We can also define J ±tot = (J 1 ,±I 2 + I 1 J 2 ,±), where Ji,± = Ji,x ± iJi,y.

There is a well defined procedure for constructing the |jm〉 states found by adding two angular momentum, using the product states |j 1 m 1 〉|j 2 m 2 〉 ≡ |j 1 m 1 ; j 2 m 2 〉 as a basis.

In brief, start with a state that has definite quantum numbers for total angular momen- tum and the z-component of angular momentum - express this state as a product state. Then apply total momentum lowering operators to this state to find the linear combina- tions of product states that give the other total J, Jz eigenstates.

  1. START. Note that there is only one state with Jz = j 1 + j 2. That is the state |j 1 j 1 ; j 2 j 2 〉. What is J^2? Well, one can write

J^2 = J 12 + J 22 + 2J 1 ,z J 2 ,z + J 1 ,+J 2 ,− + J 1 ,−J 2 ,+ ;

applying this operator to this state gives (note J 1 ,+|j 1 j 1 〉 = 0, etc.)

J^2 |j 1 j 1 ; j 2 j 2 〉 = [j 1 (j 1 + 1) + j 2 (j 2 + 1) + 2j 1 j 2 + 0 + 0]|j 1 j 1 ; j 2 j 2 〉 = (j 1 + j 2 )(j 1 + j 2 + 1)|j 1 j 1 ; j 2 j 2 〉 ,

so this state has J = j 1 + j 2. One can then conclude that

|jm〉tot = |j 1 j 1 ; j 2 j 2 〉.

  1. APPLY J− TO LOWER Jz. Given a state |kk〉tot defined in terms of the product states, construct |k, k − 1 〉, |k, k − 2 〉,.. ., |k, −k〉, by repeatedly applying J −tot , using J−|k, r〉 =

k(k + 1) − r(r − 1)|k, r − 1 〉

j=∑j 1 +j 2

j=

j − 2

j=|j (^1) ∑−j 2 |− 1

j=

j + j 1 + j 2 − j 1 + j 2 + 1

= (j 1 + j 2 + 1)(j 1 + j 2 ) − (j 1 − j 2 )(j 1 − j 2 − 1) + 2j 2 + 1 = j 12 + j^22 + 2j 1 j 2 + j 1 + j 2 − j^21 − j 22 + 2j 1 j 2 + j 1 − j 2 + 2j 2 + 1 = 4 j 1 j 2 + 2j 1 + 2j 2 + 1 = (2j 1 + 1)(2j 2 + 1).

This shows that only the states with j = |j 1 − j 2 |,... , j 1 + j 2 show up in the total angular momentum representation. This is an important result.

Part of a sample calculation

Here j 1 = 2 and j 2 = 1.

First, | 33 〉 = | 22 〉| 11 〉 = |22; 11〉.

Then apply lowering operators:

J−| 33 〉 =

12 − 6 | 32 〉 = (J 1 ,− + J 2 ,−)|22; 11〉 =

so

| 32 〉 =

Applying J− again to | 32 〉 gives

√ 12 − 2 | 31 〉 =

or

| 31 〉 =

What does this mean? It means, for example, that if I know the total J = 3 and the total Jz = 1, then the probability that the first particle has m 1 = 1 is 158. One could continue, but you don’t need to if you are interested in the higher Jz states.

For example, | 22 〉 must be orthogonal to | 32 〉 yet have Jz = 2. The only way to get Jz = 2 is by combining |21; 11〉and |22; 10〉. By inspection, it follows that

(up to a constant phase factor which is naturally chosen here). The other J = 2 states can then be found by applying J− to | 22 〉.

In summary, this calculation was done in the following steps, where for each ket in the total angular momentum representation, we compute its representation as a sum of

states in the product of the two component representations:

| 33 〉 ⇐ (Step1, Start) ⇓ (2, using J−) | 32 〉 ⇒ (4, orthogonality) | 22 〉 ⇓ (3, using J−) | 31 〉