Functional Groups, Slides of Organic Chemistry

Background: Functional groups are portions of molecules that can be recognized and also classified. Usually, in organic chemistry, it is common to see ...

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Functional*Groups!
Created!by:!Julio!Cesar!Torres!Orozco!
!!! ! ! !
!
Background:! Functional! groups! are! portions! of! molecules! that! can! be! recognized! and! also!
classified.! Usually,! in! organic! chemistry,! it! is! common! to! see! carbon?backboned?molecules! that!
have! these! functional! groups! attached! to! such! chain.! Functional! groups! give! molecules! their!
properties.!It!is!also!important!to!identify!these!functional!groups!in!order!to!name!molecules.!
Functional!Groups:!
The!following!functional!groups!will!be!listed!in!decreasing!priority!order:!
FUNCTIONAL*
GROUP*
FORMULA*
GENERAL*
FORMULA*
SUFFIX*
EXAMPLE*
*
Carboxylic*
Acids*
!
*
*
R=COOH*
*
*
=oic*acid*
Ethanoic!
acid!
*
Acid*
anhydrides*
!
*
(RC(O))2O*
*
*
=oic*
anhydride*
Formic!
anhydride!
*
Esters*
!
*
R=COOR*
*
=oate*
*
*
Acyl*
Halides*
!
*
R=COX!
*
=oyl*
halide*
*
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Created by: Julio Cesar Torres Orozco Background: Functional groups are portions of molecules that can be recognized and also classified. Usually, in organic chemistry, it is common to see carbon-­‐backboned-­‐molecules that have these functional groups attached to such chain. Functional groups give molecules their properties. It is also important to identify these functional groups in order to name molecules. Functional Groups: The following functional groups will be listed in decreasing priority order: FUNCTIONAL GROUP FORMULA GENERAL FORMULA SUFFIX EXAMPLE Carboxylic Acids R-­‐COOH -­‐oic acid (^) Ethanoic acid Acid anhydrides (RC(O)) 2 O -­‐oic anhydride Formic anhydride Esters R-­‐COOR′ -­‐oate Acyl Halides R-­‐COX -­‐oyl halide

Created by: Julio Cesar Torres Orozco Amides RCONR 2 -­‐amide Ethanamide Nitriles RCN Alkane nitrile Benzonitrile Aldehydes RCOH -­‐al Ethanal Ketones RCOR’ -­‐one Butanone Alcohols ROH -­‐ol Methanol Thiols RSH -­‐thiol Ethanethiol Primary Amines RNH 2 -­‐amine Methanamine