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Organic Chemistry – Functional Groups – Functional groups table, isomerism, IUPAC naming, reactions
Typology: Summaries
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Functional Group General Formula Example Key Properties Alkane C-C single bonds Ethane (C2H6) Non-polar; low reactivity Alkene C=C double bond Ethene (C2H4) Electrophilic addition Alkyne C≡C triple bond Ethyne (C2H2) More reactive than alkenes Alcohol -OH Ethanol (C2H5OH) H-bonding; polar; soluble in water Aldehyde -CHO Ethanal (CH3CHO) Oxidised to carboxylic acids Ketone -C(=O)- Acetone (CH3COCH3) Cannot be easily oxidised Carboxylic Acid -COOH Acetic acid Weak acid; H-bonding Ester -COO- Ethyl acetate Pleasant smell; hydrolysis Amine -NH2 Methylamine Basic; H-bonding Amide -CONH2 Acetamide Peptide bonds in proteins
Reaction Type Description Example Addition Two molecules combine into one; double/triple bond opensEthene + HBr → Bromoethane Substitution One atom/group replaced by another Methane + Cl2 → Chloromethane + HCl Elimination Small molecule removed; double bond forms Haloalkane + KOH(alc) → Alkene Condensation Two molecules join with loss of small molecule (H2O)Amino acid + amino acid → Dipeptide Hydrolysis Bond broken by reaction with water Ester + H2O → Acid + Alcohol Oxidation Loss of H or gain of O Primary alcohol → Aldehyde → Acid Reduction Gain of H or loss of O Ketone + [H] → Secondary alcohol