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The properties of heat and its effects on various phenomena and human behaviors. It explains the concept of internal energy and temperature, and the different temperature scales used to measure it. It also introduces the field of thermodynamics and its subdivision, heat transfer. The experiment aims to investigate various properties of heat.
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1. Introduction
During winter, shaking hands with someone who just entered the building will leave you feeling chilly. Drinking a cold soda on a hot summer day will make you feel cool and refreshed. Why? If you heat a kettle on the stove, the water inside the kettle boils, but the kettle doesn’t melt. If you boil water in a covered pot, the lid rattles. People usually wear light color clothes during summer and dark colors during winter. Railroad tracks are built with gaps between each rail. Heat is the reason for these phenomena and human behaviors. In this experiment, we will investigate various properties of heat.
2. Background
2.1. Heat
All objects have energy. Although energy is present in various forms, we can broadly categorize it as microscopic and macroscopic. Microscopic energy is often referred to as the internal energy of an object since it deals with energies related to the atomic and subatomic realms, internal to the material. One measurement, or indication, of a material’s internal energy is temperature. See [2, 4, 6, 8, 9] for more details. The Celsius scale references zero degrees and one hundred degrees at the temperatures at which pure water freezes and boils, respectively, at standard atmospheric pressure. The range between these two extremes is uniformly divided. The Fahrenheit scale is based on an alternate unit of temperature. The basic idea is the same as with the Celsius scale, but the reference points are defined at different temperatures. The relation between Celsius and Fahrenheit temperatures is as follows
The Celsius and Fahrenheit scales are each a measurement of an object’s relative internal energy. To measure the absolute temperature of an object the Kelvin scale is used. On the Kelvin scale the zero point is the level at which the object is completely at rest, even at the subatomic level. A change of one degree Kelvin corresponds to a change of exactly one degree Celsius. The relation between Celsius and Kelvin temperatures is as follows
2.2. Thermodynamics and heat transfer
The study of the relationships between heat and work (energy) and the systems in which energy is transferred is known as thermodynamics. Heat transfer is one concentrated subdivision within the field of thermodynamics, where the time rate of transfer is of particular interest. Referring to the heat, or temperature, of an object is merely a way of describing the object’s energy level. Heat transfer, however, refers to the transfer of energy from one location to another due to a difference in temperature. Our bodies are constantly transferring energy in the form of heat so that we may function properly. This is the reason that we run a fever when we are sick, as the body must work overtime to combat the disease. Heat transfer
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is also the principle driving force behind most energy sources that are currently available. An important aspect in the study of heat transfer and thermodynamics involves the design of energy efficient systems. There are three means through which heat transfer can take place; convection, conduction, and radiation, which we will discuss in the sequel. See [2, 4, 5, 8, 9] for more details.
Thermal equilibrium
Heat flow always occurs in the direction of lower temperatures. That is heat, or energy, flows from a hot object into a cooler one until the temperatures of the two objects become equal. At this stage we say that thermal equilibrium has been achieved. A thermometer is based on this principle. See [2, 6, 8, 9] for more details.
Thermal expansion
In our discussion on light, we see how the energy incident upon a material excites the electrons within the material. The average separation between the atoms in a material depends on the oscillation of its electrons. When the material, hence the electrons, are at lower energy levels, the amplitudes of oscillation are correspondingly small. At higher energy levels, however, the electrons oscillate with higher amplitudes. Therefore, the average separation between the atoms within the material increases. This phenomenon is known as thermal expansion. This phenomenon can be expressed in terms of either linear or volumetric expansion. See [2, 6, 8, 9] for more details.
Linear expansion
For an object with initial length Li ,we can define α ,the average coefficient of linear expansion
as follows
α
relatively small changes in temperature, α is approximately constant and the expansion is directly
∆ L =α Li ∆ T.
Table 1 lists the average coefficient of linear expansion for various materials [9].
Table 1: Average coefficients of linear expansion
Aluminum 2. Brass 2. Copper 1. Glass 0.4~0. Invar (nickel-iron alloy) 0. Quartz (fused) 0. Steel 1.
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Figure 1: Heat conduction
Table 3 lists thermal conductivities for various metals, solids, and gases [9].
Table 3: Thermal conductivities k ( W m ⋅ K )
Aluminum 205.0 Brick, insulating 0.15 Air 0. Brass 109.0 Concrete 0.8 Argon 0. Copper 385.0 Cork 0.04 Helium 0. Lead 34.7 Felt 0.04 Hydrogen 0. Mercury 8.3 Fiberglass 0.04 Oxygen 0. Silver 406.0 Glass 0. Steel 50.2 Rock wool 0. Styrofoam 0. Wood 0.12~0.
Convection
Most fluids also undergo expansion when they are heated. Thus, the density of one such fluid decreases with increasing temperature, and the fluid rises. The area vacated by the expanded fluid is occupied by cooler and heavier neighboring molecules. In turn, these molecules, which are now exposed to the heat source, expand and rise. The displaced molecules will eventually cool down and will sink. This process is cyclical and is a mechanism of heat transfer by the movement and circulation of a fluid mass called convection. There are two categories of convection, natural and forced. Natural convection occurs as a result of an induced fluid circulation due to heat transfer. Forced convection is a result of an externally induced fluid circulation. Heat transfer due to natural convection is minimal compared with forced convection. Convection ovens are a good example of using an induced air flow to heat a system. Weather patterns are greatly influenced by convection and are good example of natural convection. Convection is generally used to cool an object rather than to heat it. See [2, 6, 8, 9] for more details. Figure 2 is a diagram depicting convection.
Figure 2: Convection
Heat source
Fluid flow
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Radiation
Thus far we have discussed two forms of heat transfer where each requires a medium for the energy to travel through. Heat transfer, however, can occur in the absence of a medium as well. This form of heat transfer is known as radiation. Our planet, Earth, receives solar energy in the form of light from the Sun through radiation. Although we are at a distance of approximately 93 million miles from the sun, we gain sufficient energy because the dependency of radiation on temperature differences is quite significant. See [6, 8] for more details.
3. Equipment list
Board of Education (BOE) with Basic Stamp 2 (BS2)
The combination of the BS2 embedded within the BOE will serve as the microcontroller that monitors the experiments that you are about to do. The BS2 is a 24 pin Dual Inline Package (DIP) integrated circuit (IC). It is based on Microchip Inc.’s PIC 16C57 microcontroller. The BS2 is powered by a 6-14V direct current (VDC) power supply. An onboard voltage regulator provides a steady 5VDC output to the BS2. The BS2 comes with ROM, 2KB Electronically Erasable Programmable ROM (EEPROM), and a small amount of RAM. The BS2 is programmed in PBasic language, the instruction set that is stored in the BS2 ROM. The user defined program is downloaded into the EEPROM from a PC to the BOE using a DB-9 serial cable. The excess EEPROM can be used for long term data storage. The BS2 has 16 general purpose digital input/output (I/O) pins that are user defined. The high position on a digital I/O pin refers to a 5VDC and a low position on a digital I/O pin refers to a 0VDC (ground potential). Each pin can source (supply) a maximum current of 20mA and sink (draw) a maximum current of 25mA. The 16 I/O pins on the BS2 at any given time can source/sink a maximum of 40mA/50mA. If using an external 5VDC voltage regulator, these limits apply to each group of 8 pins, P0-P7 and P8-P15. Exceeding these current source/sink limits or establishing a voltage on a pin greater than 5VDC will damage the BS2. See [5, 7] for more details. A limitation that often arises when using the BS2 is the lack of support for floating point variables. Utilizing floating point operations like division in the absence of floating point variables may lead to mathematical errors due to truncation. The largest variable or constant that can be stored on the BS2 is of word size (16 bits), which has a numerical range of 0-65,535 in decimal notation. The program codes that will be used for the heat experiments have been written to display the temperature in units of
floating point variables. A BOE and BS2 are depicted in Figure 3 [3]. The BS2 is placed, in the same orientation as shown, in the IC socket in the lower left corner of the BOE.
Figure 3: Parallax Board of Education with a Basic Stamp 2 at right
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4. Experimental procedure
4.1. Thermal equilibrium experiment
Goals:
Thermal equilibrium experiment procedure
Discussion Is thermal equilibrium achieved instantaneously or is there a time dependency. Is there a temperature dependency? What affect does this dependency have on a real system such as a thermostat?
4.2. Conduction experiment
Goals:
Conduction experiment procedure
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Discussion Which metal is the better heat conductor [1]? Is there any correlation between heat conductivity and thermal conductivity? Do these results seem reasonable? In summer, one would like his/her house to absorb minimal heat from the outside environment without allowing the cooler air inside to escape. The reverse is true for winter, when one wants to retain as much heat as possible. Is it possible to build a wall that satisfies both demands? What material should one use? Should the wall be made from a single material or a composition? Are the walls of your house of optimal design in this consideration?
4.3. Radiation experiment (Temperature difference under colored cloths)
Goal:
Radiation experiment procedure
Discussion We have just seen that color affects the amount of heat energy that the object absorbs. For this reason it is advisable to wear light colored clothing during summer and dark colored clothing in winter. For certain applications, however, this color scheme is not possible. Jungle camouflage, for instance, has to be earthy tones, dark greens and browns. Similarly, arctic camouflage is predominately white (think of polar bears and arctic foxes). What are some other methods of controlling the heat absorption of clothing?
5. Suggested projects
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Appendix A: Circuit schematics
Figure A1: Circuit schematic for the heat experiment test bed