Introduction, MOS Capacitor Electrostatics | EEE 531, Study notes of Physics of semiconductor devices

Material Type: Notes; Class: Semiconductor Device Theory I; Subject: Electrical Engineering; University: Arizona State University - Tempe; Term: Unknown 1989;

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EEE 531: Semiconductor Device Theory I
EEE 531: Semiconductor Device Theory I
Instructor: Dragica Vasileska
Department of Electrical Engineering
Arizona State University
Topics covered:
1. Introduction
(band diagrams, fields and dielectrics)
2. MOS Capacitor Electrostatics
(A) Block-charge model
(B) Exact analytical model
(C) Self-consistent solutions (SCHRED)
EEE 531: Semiconductor Device Theory I
1. Introduction
The Si MOSFET is the most important solid-state device
for modern electronics. To understand its operation, we
first need to understand the MOS capacitors:
Semiconductor
(p-type or n-type)
Vmetal
oxide
oxide thickness
dox
pf3
pf4
pf5
pf8
pf9
pfa
pfd
pfe
pff
pf12
pf13
pf14
pf15
pf16
pf17
pf18
pf19
pf1a

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EEE 531: Semiconductor Device Theory I

EEE 531: Semiconductor Device Theory I

Instructor: Dragica Vasileska

Department of Electrical Engineering

Arizona State University

Topics covered:

1. Introduction **(band diagrams, fields and dielectrics)

  1. MOS Capacitor Electrostatics** (A) Block-charge model (B) Exact analytical model (C) Self-consistent solutions (SCHRED)

EEE 531: Semiconductor Device Theory I

1. Introduction

  • The Si MOSFET is the most important solid-state device

for modern electronics. To understand its operation, we

first need to understand the MOS capacitors:

Semiconductor (p-type or n-type)

V metal

oxide

oxide thickness dox

EEE 531: Semiconductor Device Theory I

  • Energy-band diagram of ideal MOS capacitor , for which:

M sc

E (^) FM EFS

Φ (^) M Φsc (^) sc χ

Vacuum level

F

g M sc q

E

Φ =χ + − ϕ 2

qϕ F

E C

E V

n-type semiconductor

F

g M sc q

E

Φ =χ + + ϕ 2

p-type semiconductor

E i

E FM (^) EFS

Φ M

Φ (^) sc sc χ

qϕ F

E C

E V

E i

EEE 531: Semiconductor Device Theory I

  • Ideal MOS capacitor under accumulation bias conditions:

p-type SC

G

−V

holes

d ox

−Q G

S

Q

FM

E

E FS

E C

E V

E i

Accumulation of majority holes

G qV ρ(x )

x

x-axis

Energy

EEE 531: Semiconductor Device Theory I

  • Terminology:

(a) Bulk potential:

p-type SC:

n-type SC:

(b) Potential:

(c) Surface potential:

Wf

FS

E

C

E

E V

i

E

q ϕ F

q ϕ s

q ϕ ( x ) q^ ϕ^ F =Ei(bulk)−EFS

ln > 0   

   

 ϕ = i

B A F n

N

q

kT

ln (^) < 0 

  

 ϕ =− i

B D F n

N

q

kT

q ( x) E(bulk) E(x ) i i ϕ = −

q ϕs =Ei( bulk)−Ei( 0 )

ϕ s

ϕ( x )

x

EEE 531: Semiconductor Device Theory I

  • Regions of operation for MOS capacitor with p-type SC:

(a) accumulation:

(b) depletion:

(c) inversion:

  • The condition ϕs=2 ϕF is called onset of inversion :

ϕ < 0 s

s F 0 < ϕ < 2 ϕ

s F ϕ ≥ 2 ϕ

 (^) ϕ = −  

 ϕ = 

2

exp

exp

exp

exp

s s i

s

B

F i B

i FS s i

B

F i B

FS i s i

np n

n pbulk

k T

q n k T

E E

p n

k T

q n k T

E E

n n

EEE 531: Semiconductor Device Theory I

  • Fields and dielectrics:
  • Electric field profile for a

MOS capacitor with p-

type SC under depletion

condition:

10 kε

2 0 k ε

t 1

F

Ft 2

t 1 t 2

F =F

Tangential components

k 1 ε 0

20 k ε

n 1

F

n 2

F

10 1 20 2

1 2

n n

n n k F k F

D D

ε = ε

Normal components

d o x

F(x )

x do x +W f

F o x

F sc

Fox ≈ 3 F sc

EEE 531: Semiconductor Device Theory I

EEE 531: Semiconductor Device Theory I

Instructor: Dragica Vasileska

(Notes provided by: Prof. Dieter Schroder)

Department of Electrical Engineering

Arizona State University

Topics covered:

2. MOS Capacitor Electrostatics (A) Block-charge model (B) Exact analytical model (C) Self-consistent solutions (SCHRED)

EEE 531: Semiconductor Device Theory I

Depletion:

−d o x

Q G

ρ( x )

x

W

  • qNA

Q (^) s =−qNA W

ϕs

x

ϕ( x )

0

  • The charge density is given by:
  • The boundary conditions for the 1D Poisson equation are:
  • Final expressions for the electric field, electrostatic potential and the width of the depletion region:

A ρ (x )=−qN

ϕ (W )=F(W)= 0 ,ϕ( 0 )=ϕ s

A

s s

s

A

s

A

qN

k W

W x k

qN x

W x k

qN F x

ε ϕ

ε

ϕ =

ε

0

2

0

0

G s ox

VG V =ϕ +V

EEE 531: Semiconductor Device Theory I

  • The surface potential is an internal parameter. We therefore

need to relate ϕs to the gate voltage VG using:

where:

  • Final expression for the VG-ϕs relationship:
  • Threshold voltage definition:

VG =Vox+ϕs=Foxdox+ϕ s

0 0 ε

ε

ox

A

s

A

ox

s s ox

s ox k

qN W

k

qN W

k

k F k

k F

ox

ox A s s ox ox

G s d

k qN k C C

V

0 2 0 , where

1 ε =ϕ + εϕ =

Vth = VG for which ϕs= 2 ϕ F

EEE 531: Semiconductor Device Theory I

  • Graphical representation of the VG-ϕs relationship:

ϕs ϕ (^) s = 2 ϕ F

G

V

V th

Exact solution

Delta-depletion approximation

  • Surface potential varies rapidly with VG when the device is depletion biased. Gate voltage is divided proportionally between the semiconductor and the oxide.
  • When the semiconductor is accumulated or inverted , it takes large VG to produce small change in ϕs. Changes in the applied bias are almost all dropped across the oxide.

EEE 531: Semiconductor Device Theory I

(B) Exact Analytical Model

  • To solve for the electrostatic potential and the electric field

profile under arbitrary bias conditions, one needs to go

beyond the delta-depletion approximation and use the exact

expression for the charge density ρ(x) in the 1D Poisson

equation:

  • Analytical tricks that we need to use to get to the answer:

(2) in the semiconductor bulk, where ϕ=0.

( )

( (^) D A)

V po

V po

D A

qp e n e N N

x q p n N N

= T^ −^ T+ −

ρ = − + −

− ϕ/ ϕ/

2

2

F x dx

d u d

udu

dx

d

dx

d

d

d

dx

d

dx

d

dx

d =−

ϕ

ϕ

ϕ  

 ϕ

ϕ

 ϕ

ϕ

ρ( x)= 0

EEE 531: Semiconductor Device Theory I

  • The corresponding gate voltage equals to:
  • Simulation results for NA= 16

cm

and dox=4 nm:

s ox ox

s G s ox s Fd k

k V =ϕ +V =ϕ +

-1.

-0.

0

1

2

-0.4 -0.2 0 0.2 0.4 0.6 0.8 1

V G^

[V]

ϕs [V]

2 ϕ F

VG = VTH≈ 0. 7 V

Delta approximation

ϕF= 0. 35 V

Surface potential

-2 10^12

-1.5 10^12

-1 10^12

-5 10^11

0

5 10^11

1 10^12

1.5 10^12

2 10^12

-0.4 -0.2 0 0.2 0.4 0.6 0.8 1

|Q

/q| [cms

-2]

Surface potential ϕs [V]

accumulation

depletion inversion

Sheet-charge density

EEE 531: Semiconductor Device Theory I

(C) SCHRED: Self-Consistent Schrödinger-Poisson Solver

  • SCHRED location:

http://www.ecn.purdue.edu/labs/punch/

  • Existing SCHRED Features:

Ë Classical and quantum-mechanical charge description

Fermi-Dirac and Maxwell-Boltzmann Statistics (for classical) Fermi-Dirac for quantum-mechanical calculation

Ë Single-valley and multiple-valley conduction bands

Ë Metal and poly-silicon gates

Ë Partial ionization of the impurity atoms

Ë Exchange and correlation corrections to the ground

state energy of the system

EEE 531: Semiconductor Device Theory I

  • SCHRED flow-chart:

Read data from input file

Solve Poisson’s equation

Update ρ(x)

no

Solve 1D Poisson’s equation

Update ρ(x)

no

Solve 1D Schrödinger equation

classical quantum

Converged?

Write data in files

Converged?

yes

yes

EEE 531: Semiconductor Device Theory I

  • Simulation results:

0

1

2

3

4

0 10 20 30 40 50 60 70 80

E

c^

[eV]

depth [nm]

Classical charge distribution: NA=10^18 cm-3, dox=4 nm VG=1 V

Referent level is the Fermi level (EF=0)

Conduction band edge:

0

1 10^19

2 10^19

3 10^19

4 10^19

5 10^19

10 15 20 25 30

n [cm

]

depth [nm]

Classical charge distribution NA=10^18 cm-

Electron density:

-1 10^19

-8 10^18

-6 10^18

-4 10^18

-2 10^18

0

0 1 0 20 3 0 40 5 0 60 7 0 80

ρ

(x)/q [cm

]

Depth [nm]

semiconductor charge

Charge density:

EEE 531: Semiconductor Device Theory I

  • In general, the charge in the semiconductor is represented

as a sum of the inversion layer charge density QN, depletion

layer charge density QB and the accumulation layer charge

density QP, which gives:

  • The total gate capacitance is, thus, given by:

inv depl acc s

P

s

B

s

N

s

s s C C C d

dQ

d

dQ

d

dQ

d

dQ C = + + ϕ

− ϕ

− ϕ

=− ϕ

=−

ox

ox ox

inv depl acc

ox

ox

ox s

ox tot

d

k C

C C C

C

C

C C

C

C

0

ε

Cox

Semiconductor Cinv Cdepl C^ acc capacitance Cs

EEE 531: Semiconductor Device Theory I

  • Using the analytical model expression for the semiconduc-

tor charge per unit area Qs, we get:

(A) Accumulation regime:

( )

1 / 2 / /

/ /

( ) 1 1

2 ( )

1 1

 

  

  

  

 −

ϕ − + −

ϕ ϕ = +

ϕ

− + −

= ϕ

=−

−ϕ ϕ

−ϕ ϕ

T

V s

po

po

T

V s s

s

V

po

V po

s

s s

V

e p

n

V

f e

f

e p

n e

Cso d

dQ C

s T s T

s T s T

ε

D

s so L

k C 0

Flat-band capacitance

( ) tot ox N B

s s s T C C dQ dQ

f V → ≈ 

 = =

ϕ < → ϕ ∝ −ϕ

0 , 0

0 ( ) exp / 2

The total gate capacitance is approximately equal to the

oxide capacitance.

EEE 531: Semiconductor Device Theory I

(B) Depletion regime:

In depletion regime, the inversion charge is negligible when

compared to the depletion charge. Hence:

The total capacitance is, thus, given by:

Important remarks:

Ë If NA increases, then Ctot increases.

Ë If dox increases, Ctot decreases.

s

s A

s T

s N P

s F s s T k qN V

Cso C dQ dQ

f V

ϕ

ε

ϕ

→ = 

= =

<ϕ < ϕ → ϕ ∝ ϕ

0 , (^02) / 2

0 2 ( ) / 0

s A

s ox ox

ox

depl

ox

ox

s

ox

ox tot

k qN

d k

k

C

C

C

C

C

C

C

0

0

0

2 1 1 ε

ϕ

  • ε

ε

EEE 531: Semiconductor Device Theory I

(C) Inversion regime:

  • Most of the charge induced at the

SC-oxide interface comes from the electron-hole pair generation (via recombination-generation centers).

  • The build-up of minority carriers

proceeds at a rate limited by the process of generation of electron- hole pairs.

  • Hence, depending upon the

frequency of the applied signal and the sweep-rate of the gate voltage, one can measure:

  • low-frequency (LF) CV -curves
  • high-frequency (HF) CV -curves
  • deep-depletion (DD) CV -curves

G qV

W

E FS

E C

E V

E i

EEE 531: Semiconductor Device Theory I

High-frequency CV-curve:

  • AC-frequency high, which pre-

vents the response of the mino-

rity carriers. The sweep-rate is

low, thus allowing for the gene-

ration of the inversion layer

electrons.

  • Depletion layer and total gate capacitance:

F

s A s depl N P

s F s F T k qN C C dQ dQ

f V

ϕ

ε → ≈ ≈ 

ϕ ≈ ϕ → ϕ = ϕ

0

const

k qN

C

C

C C

C

C

s A

F ox

ox

ox depl

ox tot

ε

ϕ

0

Q G

x

W f

Q s

EEE 531: Semiconductor Device Theory I

Deep-depletion CV-curve:

  • AC-frequency high, which pre-

vents the response of the mino-

rity carriers. The sweep-rate is

also high, thus preventing the

generation of the inversion layer

electrons.

  • Depletion layer and total gate capacitance:

s

s A s depl N P

s s T k qN C C dQ dQ

f V

ϕ

ε → ≈ ≈ 

= =

ϕ = ϕ

0 , (^02)

( ) / 0

s A

s ox

ox

depl

ox

ox tot

k qN

C

C

C

C

C

C

0

0

Q G

x

W

Q s

EEE 531: Semiconductor Device Theory I

What is low-frequency?

  • The SCR generation current density equals to:
  • While JSCR flows in the semiconductor, the current flowing through the

oxide is:

  • For the inversion charge to be able to respond, we must have that the

SCR current must be able to supply the required displacement current, i.e.

Example: dox=100 nm, W=1 μm, Cox=3.45× 10 -8^ F/cm^2 :

τg=10 μs, dV/dt ≤ 0.65 V/s, feff=45 Hz (not a severe constraint)

τg=1 ms, dV/dt ≤ 6.5 mV/s, feff=0.4 Hz (severe constraint)

J (^) SCR = qniW/τ g

J (^) D =CoxdV/ dt

ox g

i ox i g C

qnW C dV dt qnW dV dt τ

/ ≤ /τ → / ≤

EEE 531: Semiconductor Device Theory I

(D) SCHRED Capabilities:

  • Capable of modeling MOS capacitors with p-type

substrates

  • SCHRED is able to calculate separately the inversion

layer capacitance Cinv and the depletion layer capaci-

tance Cdepl

  • SCHRED also gives as an output the LF gate capacitance
  • With simple post-processing, one can also calculate the

HF gate capacitance, using:

depl

ox

ox

s

ox

ox tot

C

C

C

C

C

C

C

EEE 531: Semiconductor Device Theory I

4. Deviations from the ideal model

There are several factors that lead to deviation of the

measured CV-curves from what the ideal model predictions

are:

  • Work-function difference
  • Oxide charges (interface-trap, fixed-oxide, oxide-trap

and mobile oxide charges)

  • Depletion of the poly-silicon gates
  • Quantum-mechanical space-quantization effects

EEE 531: Semiconductor Device Theory I

(A) Work-function difference:

F

g M sc q

E

Φ =χ + + ϕ 2

Ideal MOS capacitor with a p-type semiconductor

E (^) FM EFS

Φ M

Φ SC (^) SC χ

qϕ F

E C

E V

E i

W

E FM (^) EFS

E C

E V

E i

Real MOS capacitor with a p-type semiconductor

−V (^) FB=ΦSC−Φ M

Φ M

Φ SC

EEE 531: Semiconductor Device Theory I

  • The flat-band voltage VFB equals the required gate voltage

to achieve flat-band conditions.

  • The workfunction difference modifies the relationship

between the surface potential and the applied bias. This

gives rise to threshold voltage shift between the ideal and

real CV-curves:

( ) G G G MS M SC q q

∆V =V −V = Φ = Φ −Φ

'^11

Voltage applied to real

MOS capacitor

Voltage applied to ideal

MOS capacitor

EEE 531: Semiconductor Device Theory I

  • Influence on the LF CV-curves:
  • Same effect is also observed on the HF and the DD CV-

curves.

0

1

-1.5 - 1 -0.5 0 0.5 1 1.5 2

Ideal MOS capacitor non-ideal MOS capacitor

Capacitance [

μF/cm

2 ]

Gate voltage [V]

N (^) A=10^16 cm- 3 ∆VG C to x = 4 nm FB