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The term “INTERmolecular forces” is used to describe the forces of attraction. BETWEEN atoms, molecules, and ions when they are placed close to each other.
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CHM 0 02 Workshop @ Chem Center Topic: Intermolecular Forces Chapter 6
There are three types of intermolecular forces: London dispersion forces (LDF), dipole- dipole interactions , and hydrogen bonding. Molecules can have any mix of these three kinds of intermolecular forces, but all substances at least have LDF. London Dispersion Forces (LDFs):
Q 1 Rank the intermolecular forces from strongest to weakest. Q2 Even though the krypton atom is electrically neutral, why would it be said to have a momentary dipole? Q3 Which substance would have greater LDFs, F 2 or I 2? Explain. Q4 What causes the dipole in polar molecules? Q5 What happens to the strength of intermolecular forces as polarity increases? Why? Q 6 Explain how hydrogen bonds are different from dipole-dipole interactions.
Intermolecular Force LDF Present in mixtures of all molecules Strongest force for nonpolar molecules Dipole-Dipole Present mixtures of molecules with permanent dipoles Hydrogen Bonding Strongest dipole-dipole interaction Present in mixtures that contain molecules with H covalently bonded to N, O, or F
In the table below:
Lewis Structure Dipole Moment: (Yes/No) Intermolecular Force?
Lewis Structure Dipole Moment: (Yes/No) Intermolecular Force?
Lewis Structure Dipole Moment: (Yes/No) Intermolecular Force?
Complete the table below:
Strong IMF Weak IMF Distance between molecules SMALL LARGE Energy it takes to separate molecules
Affinity for other molecules like itself Volatility (ability to go from liquid to gas) Boiling/ melting point Viscosity Q1 Rank gas, liquid and solid in order of increasing intermolecular forces. Q2 To go from a liquid to a gas, what must happen? Q 3 Rank from lowest to highest boiling point
Q4 Give an explanation in terms of intermolecular forces for the following differences in boiling point. a. HFHF (20° C) and HClHCl (-85° C) b. CHCl 3 CHCl3 (61° C) and CHBr 3 CHBr3 (150° C) c. Br 2 Br2 (59° C) and IClICl (97° C)