Introduction to Intermolecular Forces, Lecture notes of Molecular Chemistry

The term “INTERmolecular forces” is used to describe the forces of attraction. BETWEEN atoms, molecules, and ions when they are placed close to each other.

Typology: Lecture notes

2021/2022

Uploaded on 08/05/2022

jacqueline_nel
jacqueline_nel 🇧🇪

4.4

(242)

3.2K documents

1 / 8

Toggle sidebar

This page cannot be seen from the preview

Don't miss anything!

bg1
CHM 002 Workshop @ Chem Center
Topic: Intermolecular Forces Chapter 6
Introduction to Intermolecular Forces
The term INTERmolecular forces is used to describe the forces of attraction
BETWEEN atoms, molecules, and ions when they are placed close to each other
This is different from INTRAmolecular forces which is another word for the covalent
bonds inside molecules.
When two particles experience an intermolecular force, a positive (+) charge on one
particle is attracted to the negative (-) on the other particles.
When intermolecular forces are strong the atoms, molecules or ions are strongly
attracted to each other, and draw closer together. These are more likely to be
found in condensed states such as liquid or solid.
When intermolecular forces are weak, the atoms, molecules or ions do not have a
strong attraction for each other and move far apart.
Q1 State the difference between intermolecular forces and intramolecular forces in terms of
where they occur at the molecular level.
Q2 What is the minimum number of molecules (or atoms, ions) needed for an intermolecular
force?
Q3 When two particles experience an intermolecular force, how are the two particles
attracted to each other?
Q4 Would it be easier to separate two molecules experiencing a strong intermolecular force
or a weak intermolecular force?
pf3
pf4
pf5
pf8

Partial preview of the text

Download Introduction to Intermolecular Forces and more Lecture notes Molecular Chemistry in PDF only on Docsity!

CHM 0 02 Workshop @ Chem Center Topic: Intermolecular Forces Chapter 6

Introduction to Intermolecular Forces

  • The term “ INTER molecular forces” is used to describe the forces of attraction BETWEEN atoms, molecules, and ions when they are placed close to each other
  • This is different from INTRA molecular forces which is another word for the covalent bonds inside molecules.
  • When two particles experience an intermolecular force, a positive (+) charge on one particle is attracted to the negative (-) on the other particles.
  • When intermolecular forces are strong the atoms, molecules or ions are strongly attracted to each other, and draw closer together. These are more likely to be found in condensed states such as liquid or solid.
  • When intermolecular forces are weak , the atoms, molecules or ions do not have a strong attraction for each other and move far apart. Q1 State the difference between intermolecular forces and intramolecular forces in terms of where they occur at the molecular level. Q2 What is the minimum number of molecules (or atoms, ions) needed for an intermolecular force? Q3 When two particles experience an intermolecular force, how are the two particles attracted to each other? Q4 Would it be easier to separate two molecules experiencing a strong intermolecular force or a weak intermolecular force?

Types of Intermolecular Forces

There are three types of intermolecular forces: London dispersion forces (LDF), dipole- dipole interactions , and hydrogen bonding. Molecules can have any mix of these three kinds of intermolecular forces, but all substances at least have LDF. London Dispersion Forces (LDFs):

• LDFs exist for all substances, whether composed of polar or nonpolar

molecules

  • LDF arise from the formation of temporary instantaneous polarities across a molecule from the circulations of electrons.
  • An instantaneous polarity in one molecule may induce an opposing polarity in an adjacent molecule, resulting in a series of attractive forces among neighboring molecules.
  • Molecules with higher molecular weights have more electrons. This makes their electron clouds more deformable from nearby charges, a characteristic called polarizability.
  • As a result, molecules with higher molecular weights have higher LDF and consequently have higher melting points, boiling points and enthalpies of vaporization.

Q 1 Rank the intermolecular forces from strongest to weakest. Q2 Even though the krypton atom is electrically neutral, why would it be said to have a momentary dipole? Q3 Which substance would have greater LDFs, F 2 or I 2? Explain. Q4 What causes the dipole in polar molecules? Q5 What happens to the strength of intermolecular forces as polarity increases? Why? Q 6 Explain how hydrogen bonds are different from dipole-dipole interactions.

Identifying Intermolecular Forces

Intermolecular Force LDF Present in mixtures of all molecules Strongest force for nonpolar molecules Dipole-Dipole Present mixtures of molecules with permanent dipoles Hydrogen Bonding Strongest dipole-dipole interaction Present in mixtures that contain molecules with H covalently bonded to N, O, or F

In the table below:

  1. Draw the Lewis structure for each molecule.
  2. Determine if there is a permanent dipole moment in the molecule. (Are there polar bonds? Is the molecule asymmetrical? Can you divide it into a positive side and a negative side?)
  3. Identify the strongest intermolecular force

Molecule PF 5 CS 2 BrO−^3

Lewis Structure Dipole Moment: (Yes/No) Intermolecular Force?

Molecule NH4+^ SCl 4 BrF 5

Lewis Structure Dipole Moment: (Yes/No) Intermolecular Force?

Molecule BF 3 SCl 6 PH 3

Lewis Structure Dipole Moment: (Yes/No) Intermolecular Force?

Complete the table below:

Property

Strong IMF Weak IMF Distance between molecules SMALL LARGE Energy it takes to separate molecules

LARGE SMALL

Affinity for other molecules like itself Volatility (ability to go from liquid to gas) Boiling/ melting point Viscosity Q1 Rank gas, liquid and solid in order of increasing intermolecular forces. Q2 To go from a liquid to a gas, what must happen? Q 3 Rank from lowest to highest boiling point

Q4 Give an explanation in terms of intermolecular forces for the following differences in boiling point. a. HFHF (20° C) and HClHCl (-85° C) b. CHCl 3 CHCl3 (61° C) and CHBr 3 CHBr3 (150° C) c. Br 2 Br2 (59° C) and IClICl (97° C)