Lewis Practice.pdf, Summaries of Chemistry

For example: COH2 The H's are outer atoms, leaving C and O as candidates. C is further to the left than O, so C is the central atom. 4. Draw a bond between ...

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Practice Sheet
Electron Dot (Lewis) Structures
A Lewis or Electron Dot Structure is a convenient representation of the valence electrons in an atom.
An electron dot structure for an atom is simply the symbol for the element, surrounded by a number of dots
equal to the number of valence electrons.
Avoid a common mistake: the dots represent valence electrons only, so make sure you use only the number
of dots corresponding to the number of valence electrons.
Examples:
...
Al
..
..
C
.
.
P
.
..
.
.
.
..
.
.
.
Kr
..
Ca
.
Na
Draw lewis dot structures for an atom of each of following elements:
1. K
2. Si
3. Ar
4. As
Covalent Bonds
An atom can also achieve a noble gas configuration by sharing electrons with other atoms. When two non-
metals combine, they typically share electrons in covalent bonds and form what are know as covalent compounds.
We can draw Lewis Electron Dot Diagrams for covalent molecules to determine what type of bonds the
molecules form.
For example, consider two hydrogen atoms. Each one has one valence electron. However, both hydrogens
would like to have two electrons, to obtain the same configuration as [He]. To do this, each H atom shares
an electron with the other, forming a covalent bond. In H2, each H atom has 2 electrons.
each H has 1 e−
and wants 1 more shared pairs can
be represented as
lines between atoms
a hydrogen
molecule
(diatomic = 2 atoms)
H H H2
+
H H H H
H’s share e−’s
forming a covalent
bond
. . .
.
Here’s another example, this time for chlorine. A Cl atom has 7 valence electrons, so it needs 1 more to
achieve an octet (8 electrons).
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
..
.
.
..
.
.
.
forming a covalent
2
molecule
and wants 1 more
each Cl has 7 e−
Cl
a chlorine
+
Cl Cl Cl Cl ClCl
. .
each Cl shares 1 e−’s
bond consisting of
2 electrons the shared electron pair
is represented as a line
Each chlorine now has 8 electrons, because you can count the shared ones:
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Practice Sheet

Electron Dot (Lewis) Structures

A Lewis or Electron Dot Structure is a convenient representation of the valence electrons in an atom.

An electron dot structure for an atom is simply the symbol for the element, surrounded by a number of dots equal to the number of valence electrons.

Avoid a common mistake: the dots represent valence electrons only, so make sure you use only the number of dots corresponding to the number of valence electrons.

Examples:

. .

. Al .

. .

.C^ .. P

. . .

.. ..^

..^

.^ ..Kr

. Na. Ca

  • Draw lewis dot structures for an atom of each of following elements:
    1. K
    2. Si
      1. Ar
      2. As

Covalent Bonds

An atom can also achieve a noble gas configuration by sharing electrons with other atoms. When two non- metals combine, they typically share electrons in covalent bonds and form what are know as covalent compounds. We can draw Lewis Electron Dot Diagrams for covalent molecules to determine what type of bonds the molecules form.

For example, consider two hydrogen atoms. Each one has one valence electron. However, both hydrogens would like to have two electrons, to obtain the same configuration as [He]. To do this, each H atom shares an electron with the other, forming a covalent bond. In H 2 , each H atom has 2 electrons.

each H has 1 e− and wants 1 more

shared pairs can be represented as lines between atoms

a hydrogen molecule (diatomic = 2 atoms)

H^ + H H H H H H 2

H’s share e−’s forming a covalent bond

.. ..

Here’s another example, this time for chlorine. A Cl atom has 7 valence electrons, so it needs 1 more to achieve an octet (8 electrons).

.. .. .. .. .. .. .. .. .. .. ..

. . . . . . . . . . . . .

...

forming a covalent

2

molecule

and wants 1 more

each Cl has 7 e−

Cl

a chlorine

Cl.^ +. Cl Cl Cl Cl Cl

each Cl shares 1 e−’s

bond consisting of 2 electrons the shared electron pair is represented as a line

Each chlorine now has 8 electrons, because you can count the shared ones:

..

.. ..

.

. .

. .

...

Cl Cl

this Cl atom also has an octet

this Cl now has an octet of 8 electrons

Sometimes you need to share more than one pair of electrons to achieve an octet:

.. .. .. ..

. . .. ..

. . . . . ..^. . . . . . . 2

molecule

O^ + O O O O O O

each O has 6 e− and wants 2 more

forming a double covalent bond

an oxygen each O shares 2e−’s

the four shared electrons

.. ..

are represented as two lines between the atoms

We can check to see that each oxygen has the appropriate number of electrons:

.

. .

. .. ..

.

. .

.

O O

each oxygen atom now has an octet

total # valence electrons = 12 (note the 12 dots)

For the following problems, calculate the total number of valence electrons in each of the following molecules. Then, draw lewis dot structures for each:

  • Br 2 # valence e−
  • HCl # valence e−
  • HBr # valence e−
  • N 2 # valence e−
  • NO # valence e− This one is tricky, there is no way to achieve an octet. So, get each atom as close to an octet as possible without going over.
  • SiH 4 # valence e−
  • CCl 4 # valence e−
  • PCl 3 # valence e−
  • NCl 3 # valence e−
  • CS 2 # valence e−
  • CH 2 Cl 2 # valence e−