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Mechanics, Physics, Oscillations, Lagrangian, Solving Lagrange’s Equations, Reality of Eigenvectors, Positive Definiteness, Normalization, Principal Axis Transformation, Normal Coordinates, Initial Conditions, Linear Triatomic Molecule, Degenerate Solutions.
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What We Did Last Time ^
Reduced into 1-dimensional problem of
^
Qualitative behavior
Precession + nutation
^
Initial condition vs. behavior
^
, where
q
m
is the gyromagnetic ratio
^
precesses in magnetic field by
ω
Problem Definition ^
^
Generalized coordinates {
q^1
qn
^
must be minimum at a stable equilibrium
^
0
i
V i
q ⎛^
Potential
V is at
an extremum^2
0
0
0
i^
i^
j
i^
i^
j
ij^
i^
j
q^
q^
q^
0 i^
i^
i
q^
q
constant
zero
Constantsymmetricmatrix
Problem Definition ^
nd
This requires that the transformation functions do notexplicitly depend on time, i.e. ^
ij^
1
1
ij^
n^
i^
j^
ij^
i^
j
m
q^
q^
q q
m
(^
)^0
0 ij
ij^
ij^
k^
ij
m k
m
m
q
ij^
i^
j
T
T
1 (^
i^
i^
N
q^
q^
x^
x^
t
Constantsymmetricmatrix
Solving Lagrange’s Equations ^
^
Solution can be found by n
-th order polynomial of
Expect
n
solutions for
must be real and
ij^
j^
ij^
j
i^ t
i^
i Ca e
ω
−
=
2
ij^
j^
ij^
j
T a
V a
ω−^
Va
Ta
or 0
λ−
Can be proven by
a bit of work
2
Reality of Eigenvalues ^
Take adjoint (complex conjugate + transpose) Multiplying by
a
†^ or
a
gives
^
Writing
a
as
α
i β
(α
and
β
are real)
^
Since
is positive for any real
Va
Ta
†^
†^
*^
†
a Va
a Ta
a Ta
†^
*^
†
a V
a T *^
†
a Ta
†^
i^
i^
i
a Ta
α^
β^
α^
β^
αT
α^
βT
β^
αT
β^
βT
α
zero
1 2 T^
ηT
η ^
η
†^
a Ta
αT
α^
βT
β
= 0, i.e.
is real
^
^
Positive Definiteness
aVa
aTa
aVa aTa
Positive because^ Already shown to be positive
for any real
η
if V is minimum at the equilibrium
1 2
ηV
η
λ^
ω
i^ t C e
ω−
η^
a^
2
Normalization ^
λ Ta
^
a^
a^
can absorb such scale as well as imaginary phase
^
We fix the normalization by declaring^
Just the sign (±) remains ambiguous ^
This turns
aTa
aVa aTa
aVa
Normal Coordinates ^
Once we have
, we can switch to new coordinates
^
-^
does exist because
^
Lagrangian becomes ^
Solutions are obvious
ij^
i^
j^
ij^
i^
j
η η
η η
ηT
η^
ηV
η
(^1) − ≡ ζ
η 1
k^
k^
k^
k^
k
ζ ζ
λ ζ ζ
ζ
ζATA
ζ^
ζAVA
ζ^
ζλζ
ζ
k^
k^
k
ζ^
λ ζ = − ^
i^ tk
k^
C ek
ω
ζ^
−
=^
(^2) k^
k
ω^
Normal coordinates
No cross terms
Normal coordinates are independent simple harmonic oscillators
Initial Conditions ^
^
Suppose at
t^
^
Using
^
i^ t^ k
k^
k C e
ω
ζ^
−
=
η^
η^
η^
η ^
η^
ζ
Re(
Im
j^
jk^
k^
k^
jk^
k^
k
a^
i^
a^
Rememberto take thereal part!
Re
k^
lk^
lj^
j
a T
Im
k^
lk^
lj^
j
k
C^
a T
no sum over
k
Re
j^
jk^
k
a^
η^
ζ
Linear Triatomic Molecule
^
Solutions are
2
2
2
2 0
k^
m
k
k^
k^
m
k
k^
k^
m
2
2
k^
m
k^
m
1
ω^
2
k m
3
3 k m
1
m
a^
2
m
a^
3
m
a
Is this OK?
Linear Triatomic Molecule ^
This is not an “oscillation” Consider it as an oscillation with infinitely long period Although
is minimum at the equilibrium, it does not
increase when the whole molecule is shifted^
Position of the CoM is a cyclic coordinate Total momentum is conserved 1
1
m
a^
m
m
m
Linear Triatomic Molecule ^
3
^
Normal coordinates are
is cyclic as we expect
m
1
m
−
1
1
2
3
m
2
1
3
( 2
m
3
1
2
3
m
2
2
2
2
2
1
2
3
2
3
k 2
m
ζ^
ζ^
ζ
ζ^
ζ
Degenerate Solutions ^
λ j
λ k
^
What if the eigenvalue equation has multiple roots? ^
Can we still achieve
^
Multiple root corresponds to multiple eigenvectors Any linear combination
c^ j
a j^
is also an eigenvector
^
It is always possible to find a set of
m
orthogonal vectors
m^ f
λ^
λ^
κ^
λ
λ^ =
κ^ is an
m
-fold root
j^
j^
m
T a
m^
eigenvectors