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Hybridisation of an atom-H = No. of σ bonds + No. of lone pairs Selection of Principle Carbon Chain-1. Principal functional group 2. Maximum number of multiple bonds 3. Maximum number of Carbon atoms 4. Maximum number of substituents Carboxylic acids--COOH -oic acid Sulphonic acids--SO3H -sulphonic acid Acid anhydride-R-C(=O)-O-C(=O)-R -oic anhydride Esters-RCOOR -oate Acid halides-RCOX oyl halide
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Hybridisation of an atom-✓✓H = No. of σ bonds + No. of lone pairs Selection of Principle Carbon Chain-✓✓1. Principal functional group
Halo-✓✓-X Hydroxy-✓✓-OH Alkoxy (Ether)-✓✓-OR Amino-✓✓-NH Cyano-✓✓-CN Formyl or oxo-✓✓-CHO Oxo-✓✓>C=O Carboxy-✓✓-COOH Nitro-✓✓-NO As Electronegativity increases-✓✓Stability of carbanion increases, stability of carbocation decreases Stability of Carbocation α-✓✓+I/-I Stability of Carbanion α-✓✓-I/+I