Problem Set 2 in Physics 324: Infinite Square Well Potential and Expectation Values, Assignments of Quantum Mechanics

Problem set 2 for physics 324, which involves finding the normalization constant, expectation value of position, and deriving an expression for the amplitude of energy eigenstates for a particle in an infinite square well potential. It also includes calculating the expectation values of energy, position, and linear momentum for a particle in a superposition of energy eigenstates.

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Uploaded on 03/11/2009

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Physics 324 Problem Set # 2 Due 10/13/03
1. Problem 2.5 in your textbook.
2. For the infinite square well potential (V(x) = 0 for 0 xaand infinite elsewhere),
a particle is prepared in the state ψ(x, 0) at time t= 0 where:
ψ(x, 0) = Bx for 0 xa; and ψ(x, 0) = 0 elsewhere.
Note, this is an unphysical wavefunction because it must change suddenly from a value
of Ba at x=ato a value of 0 at x=a. (Fourier analysis nonetheless allows us to express
such a function, or a square wave for example, as a sum of well behaved functions (sines and
cosines).
(a) Find the normalization constant, B.
(b) Find the expectation value of the particle’s position, hx(0)iat time t=0.
(c) We can express ψ(x, 0) as a sum of energy eigenstates, because the energy eigen-
states form a complete orthonormal set:
ψ(x, 0) =
X
n=1
cnψn(x)
where ψn(x) are the solutions to the time independent Schrodinger equation for the
infinite square well potential (energy eigenstates) as given in your text.
Derive an expression for cn, the amplitude of energy eigenstate, n, in the expansion for
ψ(x, 0).
(d) Write an expression for ψ(x, t), that is, an expression for the wave function at all
times t0.
3. A particle in an infinite square well potential (same potential as Problem #2)is
prepared in a state:
ψ(x, t)=A[ψ1(x)eiE1t/¯h+i2ψ4(x)eiE4t/¯h]
where ψi(x) is the solution to the time independent Schrodinger equation for energy Ei.
(a) Use the orthonormality of the ψi’s to compute the normalization constant, A.
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Physics 324 Problem Set # 2 Due 10/13/

  1. Problem 2.5 in your textbook.
  2. For the infinite square well potential (V (x) = 0 for 0 ≤ x ≤ a and infinite elsewhere), a particle is prepared in the state ψ(x, 0) at time t = 0 where:

ψ(x, 0) = Bx for 0 ≤ x ≤ a; and ψ(x, 0) = 0 elsewhere.

Note, this is an unphysical wavefunction because it must change suddenly from a value of Ba at x = a to a value of 0 at x = a. (Fourier analysis nonetheless allows us to express such a function, or a square wave for example, as a sum of well behaved functions (sines and cosines).

(a) Find the normalization constant, B. (b) Find the expectation value of the particle’s position, 〈x(0)〉 at time t = 0. (c) We can express ψ(x, 0) as a sum of energy eigenstates, because the energy eigen- states form a complete orthonormal set:

ψ(x, 0) =

∑^ ∞

n=

cnψn(x)

where ψn(x) are the solutions to the time independent Schrodinger equation for the infinite square well potential (energy eigenstates) as given in your text.

Derive an expression for cn, the amplitude of energy eigenstate, n, in the expansion for ψ(x, 0).

(d) Write an expression for ψ(x, t), that is, an expression for the wave function at all times t ≥ 0.

  1. A particle in an infinite square well potential (same potential as Problem # 2) is prepared in a state:

ψ(x, t) = A[ψ 1 (x)e−iE^1 t/¯h^ + i

2 ψ 4 (x)e−iE^4 t/¯h]

where ψi(x) is the solution to the time independent Schrodinger equation for energy Ei. (a) Use the orthonormality of the ψi’s to compute the normalization constant, A.

(b) Use the results of Problem 2.10 in your text to compute 〈 Hˆ〉, the expectation value of the energy for state ψ(x, t).

(c) Calculate 〈x〉, the expectation value of the position in state ψ(x, t). (d) Calculate 〈p〉, the expectation value of the linear momentum in the x direction for state ψ(x, t).

  1. A particle of mass, m, is bound in the potential well shown below. The ground state has energy E 0.

Sketch the wave function for a very highly excited energy state of this potential well. (i.e. for a state with energy much greater than E 0 .) Explain your reasoning.

Draw the wave function for a very massive particle bound in this same potential well in an energy eigenstate with energy, E 0 , equal to the ground state energy of the lighter particle. Explain your answer.

- 3a - a 0 a 3a

x

U(x)

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