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The solutions to homework problem 9 in a quantum mechanics course, focusing on the calculation of the expectation value of position and energy for a particle in a one-dimensional box. The derivation of the expectation value of position using the wave function of the particle and the normalization condition. It also covers the calculation of the energy eigenvalues and the energy transition between different states.
Typology: Exercises
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1a) The expectation value of position is given by ∫ (^) L
0
Ψ∗xΨdx =
0
sin
( (^) nπx L
eiωtx
sin
( (^) nπx L
e−iωtdx (1)
0
sin^2 (nπx/L)xdx (2)
The time dependent parts cancel out in this case, as the eigenstates are station- ary states. We can write the integral as
〈x〉 =
0
sin^2 (ax)xdx where a = nπ/L (3)
and going to an online integrator we find ∫ sin^2 (ax)xdx =
x^2 4
cos(2ax) 8 a^2
x sin(2ax) 4 a
Now we must evaluate the integral at the limits 0 and L. The cosine term is equal to 1 at both the x = 0 and x = L and so cancels, while the sine term is zero at both x = 0, L. So the only remaining non-zero term is the first term evaluated at L, which gives L^2 /4. So
〈x〉 =
or midway in the box, which is what we expect for the average just by looking at the pictures.
1b) The superposition of the first two states is
sin
( (^) πx L
eiω^1 t^ +
sin
2 πx L
eiω^2 t
Multiplying this by its complex conjugate gives the probability distribution
|Ψ|^2 = C^2
sin^2
( (^) πx L
2 πx L
( (^) πx L
sin
2 πx L
ei(ω^1 −ω^2 )t^ + e−i(ω^1 −ω^2 )t
we see there is a cross term with time dependence that does not go away. In fact this cross-term is just a cosine!
sin^2
( (^) πx L
2 πx L
( (^) πx L
sin
2 πx L
cos(∆ωt)
where ∆ω = ω 1 − ω2. This looks a lot like when we added intensities for EM waves – there was a cross-term. We have to choose the constant C so that the probability distribution is normalized, that is
∫ (^) L
0
|Ψ|^2 dx = 1 (9)
We already know from the eigenstates that that the integrals of the first two terms in |Ψ|^2 are each L/2, and the third term is zero. So we find
∫ (^) L
0
|Ψ|^2 dx = C^2
from this we see that C^2 = 1/2 or C =
1d) To get the expectation value we just need
〈x〉 =
0
Ψ∗xΨdx =
0
|Ψ^2 |xdx (11)
where the |Ψ^2 | is given above. We know from part 1a) that the integral of the first two terms each just give L/2 so we just need to do the last integral. Doing so we find
〈x〉 =
9 π^2
cos(∆ωt) (12)
3a) Looking up the spherical Laplacian, and setting all theta and phi derivatives to zero, and V = 0 the time-independent Schrodinger equation is
2 m
r^2
∂r
r^2 ∂ψ ∂r^2
= Eψ (13)
making the suggested substitution u = ψ/r and carrying out the chain rule we find ∂^2 u ∂r^2
= k^2 ψ (14)
with k = (2mE/ℏ^2 )^1 /^2. The solution is just
u(r) = A sin(kr) + B cos(kr) (15)