Strontium Nitrate, Low Barium: Safety Data Sheet, Lecture notes of Engineering

Safety information for the handling and use of Strontium Nitrate, a low barium compound. It includes hazard identification, composition, exposure limits, physical and chemical properties, toxicological information, and ecotoxicity effects. The document also specifies hazardous decomposition products and provides instructions for accidental release measures.

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C H E M I C A L P R O D U C T S C O R P O R A T I O N SDS No. 174
G H S S A F E T Y D AT A S H E E T
1 . I D E N T I F I C A T I O N
P r o d u c t N a m e :
NAME: Strontium Nitrate, Low Barium.
SYNONYMS: Nitric Acid, Strontium Salt.
Re co mm en de d for indu st rial use in:
Ma nu fa cture of pyr ot echn ic al products
Ma nu fa cture of other strontium substances
Us e as rea ctive pr oc es si ng a id
Ra w ma te ri al i n th e ch em ic al i nd us tr y
Ra w ma te ri al i n th e el ec tr on ic i nd us tr y
SUPPLIER: C h e m i c a l P r o d u c t s C o r p o r a t i o n ( C P C )
P. O . B o x 2 4 7 0
1 0 2 O l d M i l l R o a d , S . E .
C a r t e r s v i l l e , G e o r g i a 3 0 1 2 0
Tel ep ho ne : 77 0- 38 2- 21 44
Transportation Em erge nc y: CH EM TR EC 80 0- 42 4- 93 00
2 . H A Z A R D S I D E N T I F I C A T I O N
Cl as si fica tion o f the su bsta nce or m ix tu re i n acco rdance
wi th 29 CF R 1910
Ox idizing solid (Categ ory 3), H272
Acute to xi ci ty, O ral (Category 4), H302
Skin irritation (Category 2), H315
Ey e ir ri ta ti on (Ca tego ry 2 A), H3 19
Spec ific target organ toxi ci ty - s ingl e ex po su re ( Cate go ry 3),
Re sp iratory syst em, H335
Si gn al wor d Warning
Doc. No. SRC 51-174
Rev. 1
Rev. Date 5/2015
Revision Date May 6, 2015
Page 1 of 9 pages
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C H E M I C A L P R O D U C T S C O R P O R A T I O N SDS No. 174

G H S S A F E T Y D ATA S H E E T

1. I D E N T I F I C A T I O N

P r o d u c t N a m e :

NAME: Strontium Nitrate, Low Barium.

SYNONYMS: Nitric Acid, Strontium Salt.

Recommended for industrial use in:

  • Manufacture of pyrotechnical products
  • Manufacture of other strontium substances
  • Use as reactive processing aid
  • Raw material in the chemical industry
  • Raw material in the electronic industry

SUPPLIER: C h e m i c a l P r o d u c t s C o r p o r a t i o n ( C P C )

P. O. B o x 2 4 7 0

1 0 2 O l d M i l l R o a d , S. E.

C a r t e r s v i l l e , G e o r g i a 3 0 1 2 0

Telephone: 770-382-

Transportation Emergency: CHEMTREC 800-424-

2. H A Z A R D S I D E N T I F I C A T I O N

Classification of the substance or mixture in accordance

with 29 CFR 1910

Oxidizing solid (Category 3), H

Acute toxicity, Oral (Category 4), H

Skin irritation (Category 2), H

Eye irritation (Category 2A), H

Specific target organ toxicity - single exposure (Category 3),

Respiratory system, H

Signal word Warning

Rev. 1 Rev. Date 5/

Revision Date May 6, 2015 Page 1 of 9 pages

Chemical Products Corporation SDS No. 174 Page 2 of 9 pages

Strontium Nitrate, Low Barium

Hazard statements

H272 May intensify fire; oxidizer.

H302 Harmful if swallowed.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

Precautionary statements

P210 Keep away from heat.

P220 Keep/Store away from clothing/ combustible materials.

P221 Take any precaution to avoid mixing with combustibles.

P261 Avoid breathing dust.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/ protective clothing/ eye protection/

face protection.

P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/

physician if you feel unwell.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P304 + P340 IF INHALED: Remove victim to fresh air and keep at

rest in a position comfortable for breathing.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and easy to

do. Continue rinsing.

P312 Call a POISON CENTER or doctor if you feel unwell.

P321 Specific treatment (see supplemental first aid instructions

on this label).

P330 Rinse mouth.

P332 + P313 If skin irritation occurs: Get medical attention.

P337 + P313 If eye irritation persists: Get medical attention.

P362 Take off contaminated clothing and wash before reuse.

P370 + P378 In case of fire: Use dry sand, dry chemical or

alcohol-resistant foam for extinction.

P403 + P233 Store in a well-ventilated place. Keep container

tightly closed.

P405 Store locked up.

Rev. 1 Rev. Date 5/

Chemical Products Corporation SDS No. 174 Page 4 of 9 pages

Strontium Nitrate, Low Barium

General Hazard: This product is an oxidizer. Spontaneous chemical reaction with low flash point organics or reducing agents may occur. Do not flush down sewers or other drainage systems. Exposed firefighters must wear NIOSH- approved positive pressure self-contained breathing apparatus with full-face mask and full protective clothing.

Fire Fighting Instructions: No special instructions.

Fire Fighting Equipment: Use self-contained breathing apparatus.

Hazardous Combustion Products: Toxic fumes of nitrogen oxides may be generated.

6. A C C I D E N T A L R E L E A S E M E A S U R E S

Keep away from incompatible products. Keep away from water. Should not be released into the environment. If the product contaminates rivers and lakes, or drains inform respective authorities.

Small Spill: Sweep or scoop up spilled material.

Large Spill: Try to keep material dry. Avoid contact with organics or reducing agents. Scoop up spilled material and dispose of in accordance with local, state, and federal regulations.

Pick up and arrange disposal without creating dust. Keep in properly labeled containers. Do not mix waste streams during collection. Keep in suitable, closed containers for disposal. Never return spills to original containers for re-use.

7. H A N D L I N G A N D S T O R A G E

Storage Temperature: Not critical.

Storage Pressure: Not critical.

Handling: Ensure adequate ventilation. Keep away from heat and sources of ignition. Keep away from Incompatible products. Use only clean and dry utensils. Never return unused material to storage receptacle. Keep away from water. Avoid contact with skin and eyes. Storage: Keep only in the original container. Store in a receptacle equipped with a vent. Store in a well-ventilated place. Keep cool. Keep in a dry place. - Keep in properly labeled containers.

Rev. 1 Rev. Date 5/

Chemical Products Corporation SDS No. 174 Page 5 of 9 pages

Strontium Nitrate, Low Barium

Keep container closed. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid dust formation. Take measures to prevent the build up of electrostatic charge. Ensure all equipment is electrically grounded before beginning transfer operations. Keep away from Incompatible products.

8. E X P O S U R E C O N T R O L S / P E R S O N A L P R O T E C T I O N

Engineering Controls: Control airborne concentrations below the exposure limits. Use only with adequate ventilation.

Respiratory Protection: Use a NIOSH-approved dust mask if excessive dust is present.

Skin Protection: Cover exposed skin areas and wear general-purpose gloves.

Eye Protection: Wear safety glasses. Use chemical goggles if excessive dust is present.

9. P H Y S I C A L A N D C H E M I C A L P R O P E R T I E S

Physical State: Solid.

Vapor Pressure: Not applicable.

Specific Gravity: about 3.

Solubility in Water: 667 - 802 g/l at 25 Deg. C. (77 Deg. F.)

pH: 5-

Boiling Point: Not applicable.

Melting Point: Decomposes at about 500 oC. producing oxides of nitrogen.

Vapor Density: Not applicable.

Evaporation Rate: Not applicable.

Odor: None.

Appearance: White crystalline powder or granules.

1 0. S T A B I L I T Y A N D R E A C T I V I T Y

Chemical Stability: Stable in the absence of heat or shock.

To avoid thermal decomposition, do not overheat.

Materials to avoid: Water, Acids, Powdered metal salts, Reducing agents, Organic materials, Flammable materials, Combustible material, PVC.

Rev. 1 Rev. Date 5/

Chemical Products Corporation SDS No. 174 Page 7 of 9 pages

Strontium Nitrate, Low Barium

Aspiration hazard no data available

Additional Information

RTECS: WK

1 2. E C O L O G I C A L I N F O R M A T I O N

Distribution: The element strontium is widely distributed in the natural environment. Ecotoxicity effects: Acute toxicity

  • Fishes, Cyprinus carpio, LC50, 96 h, > 97.45 mg/l
  • Fishes, Brachydanio rerio, NOEC, mortality, 34 d, >= 100 mg/l Chronic toxicity
  • Crustaceans, Daphnia magna, LC50, 48 h, 125 mg/l (Strontium chloride anhydrous)
  • Crustaceans, Daphnia magna, NOEC, 21 d, 21 mg/l (Strontium chloride anhydrous)
  • Pseudokirchneriella subcapitata (green algae), EC50, Growth rate, 72 h,

104.7 mg/l

  • Pseudokirchneriella subcapitata (green algae), NOEC, 72 h, >= 104. mg/l Mobility – Water: considerable solubility and mobility
  • Soil/sediments: considerable adsorption

Persistence and degradability - Abiotic degradation: No data available

Biodegradation: The methods for determining biodegradability are not applicable

to inorganic substances. Bioaccumulative potential - Bioconcentration: potential accumulation of the cation

Other adverse effects - No data available

1 3. W A S T E M A N A G E M E N T I N F O R M A T I O N

If disposed of in its purchased form, this product is a hazardous waste because of the small amount of soluble barium in the product. More than 100 ppm soluble barium in the TCLP extract of a waste renders it a D005 RCRA hazardous waste. This is equal to 0.2 % soluble barium in a waste. This product contains soluble barium in excess of 0.2%. The barium in this product can be rendered non-leachable/insoluble by reacting it with sulfuric acid or any soluble sulfate to form highly-insoluble barium sulfate. Barium sulfate is not a RCRA hazardous waste because it is not soluble.

Rev. 1 Rev. Date 5/

Chemical Products Corporation SDS No. 174 Page 8 of 9 pages

Strontium Nitrate, Low Barium

1 4. T R A N S P O R T I N F O R M A T I O N

U.S.A.

D.O.T. Proper Shipping Name........... : Strontium nitrate. Packing Group.....................: III D.O.T. Hazard Class............................ : 5.1 Oxidizer. U.N./N.A. Number................................... : UN 1507 Product R.Q. (lbs)................................... : None. Marine pollutant........................: No

Poison Inhalation Hazard...............: No

Product Label................................ : Strontium Nitrate.

IMDG

UN number: 1507 Class: 5.1 Packing group: III EMS-No: F-A, S-Q

Proper shipping name: STRONTIUM NITRATE

Marine pollutant: No

IATA UN number: 1507 Class: 5.1 Packing group: III

Proper shipping name: Strontium nitrate

1 5. R E G U L A T O R Y I N F O R M A T I O N

U.S. Federal Regulations: Comprehensive Environmental Response and Liability Act of 1980 (CERCLA): There is no reportable quantity (RQ) for this material.

Toxic Substances Control Act (TSCA): All components of this product are included on the TSCA inventory.

Clean Water Act (CWA):

Clean Air Act (CAA):

Superfund Amendments and Reauthorization Act (SARA) Title III Information:

SARA Section 311/312 (40 CFR 370) Hazard Categories: Immediate Hazard: X Delayed Hazard: Fire Hazard: Pressure Hazard: Reactivity Hazard: X

Rev. 1 Rev. Date 5/