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Material Safety Data Sheet for Barium Bromide Dihydrate, Slides of Engineering

University of Rhode Island (URI)Engineering

A material safety data sheet (msds) for barium bromide dihydrate, 99%. It provides information on the product's composition, hazards, first aid measures, fire fighting measures, accidental release measures, exposure limits, personal protective equipment, physical and chemical properties, stability and reactivity, toxicological information, ecological information, disposal considerations, transport information, regulatory information, and additional information. The msds includes catalog numbers, synonyms, company identification, and emergency contact information.

Typology: Slides

2021/2022

Uploaded on 09/27/2022

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Material Safety Data Sheet
Barium bromide dihydrate, 99%
ACC # 10 358
Section 1 - Chemical Product and Company Identification
MSDS Name: Barium bromide dihydrate, 99%
Catalog Numbers: AC206280000, AC206282500
Synonyms: Barium dibromide dihydrate.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
CAS # Chemical Name Perce nt EINECS /ELINC S
779 1-28 -8 Bariu m bro mide dih ydra te 99 unlis ted
Section 3 - Hazards Identification
EM ER G ENC Y O VE RV IEW
Appearance: white powder.
Wa rn ing! Harmful if inhaled or swallowed. May cause eye, skin, and respiratory t ract irritation. Hygrosco pic (absorbs moisture from the
air).
Target Organs: Kidneys, heart, liver, spleen, gast rointestinal syst em, muscles, bone marrow, nervous system.
Potential Health Effects
Eye: May cause eye irritation.
Skin: May c ause skin irritation.
Ingestion: May c ause kidney, liver and spleen damage. The barium ion is a muscle poison c ausing stimulation and then paralysis. Initial
symptoms are gastrointest inal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation
with tingling in the extremities. T he barium ion is a muscle poison c ausing stimulation and then paralysis. Initial symptoms are
gastrointest inal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with t ingling in
the extremities. The barium ion is a muscle poison causing st imulation and then paralysis. Initial symptoms are gastrointestinal, including
nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with t ingling in the extremities. Barium
deposition may result in increased de nsity of bones.
Inhalation: Harmful if inhaled. The t oxicological properties of this subst ance have not been fully investigate d. Inhalation of dust may
cause respiratory tract irritation. Inhalation at high conc entrat ions may c ause CNS depression and asphixiation.
Chronic: Inhalation at high concent rations may cause CNS depression and asphixiation.
Section 4 - First Aid Measures
Eyes: F lush eyes with plenty of wa ter for at least 15 minutes, oc ca sionally lifting the upper and lower eye lids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of wat er for at least 15 minutes while removing contaminated clot hing and shoes. Wash
clothing before reuse.
Ingestion: Never give anything by mouth to an unc onsc ious person. Get medical aid. Do NOT induce v omiting. If consc ious and alert,
rinse mouth and drink 2-4 c upfuls of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use
mouth-t o-mouth resusc itation. If breat hing has cease d apply artificial respiration using oxygen and a suitable mechanical device suc h as
a bag and a mask.
Notes to Physician: Institute cardiac monitoring for all significant ingestions of soluble barium salts. Institute ca rdiac monitoring for all
significant ingestions of soluble barium salts.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-c ontained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or
equivalent), and full protec tive gear. During a fire, irritating and highly toxic gases may be generat ed by t hermal decomposition or
combustion. Substanc e is noncombustible.
Extinguishing Media: Substance is nonc ombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Insta bility: 0
Section 6 - Accidental Release Measures
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Material Safety Data Sheet

Barium bromide dihydrate, 99%

ACC# 10358

Section 1 - Chemical Product and Company Identification

MSDS Name: Barium bromide dihydrate, 99% Catalog Numbers: AC206280000, AC Synonyms: Barium dibromide dihydrate. Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS- For emergencies in the US, call CHEMTREC: 800-424-

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS 7791-28-8 Barium bromide dihydrate 99 unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white powder.

Warning! Harmful if inhaled or swallowed. May cause eye, skin, and respiratory tract irritation. Hygroscopic (absorbs moisture from the

air). Target Organs: Kidneys, heart, liver, spleen, gastrointestinal system, muscles, bone marrow, nervous system. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause kidney, liver and spleen damage. The barium ion is a muscle poison causing stimulation and then paralysis. Initial symptoms are gastrointestinal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with tingling in the extremities. The barium ion is a muscle poison causing stimulation and then paralysis. Initial symptoms are gastrointestinal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with tingling in the extremities. The barium ion is a muscle poison causing stimulation and then paralysis. Initial symptoms are gastrointestinal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with tingling in the extremities. Barium deposition may result in increased density of bones. Inhalation: Harmful if inhaled. The toxicological properties of this substance have not been fully investigated. Inhalation of dust may cause respiratory tract irritation. Inhalation at high concentrations may cause CNS depression and asphixiation. Chronic: Inhalation at high concentrations may cause CNS depression and asphixiation.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Institute cardiac monitoring for all significant ingestions of soluble barium salts. Institute cardiac monitoring for all significant ingestions of soluble barium salts.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is noncombustible. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Flash Point: Not available. Autoignition Temperature: Not available. Explosion Limits, Lower: Not available. Upper: Not available. NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Wash area with soap and water. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a cool, dry place. Store in a tightly closed container. Store protected from moisture. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits Chemical Name ACGIH NIOSH OSHA - Final PELs Barium bromide dihydrate 0.5 mg/m3 TW A Barium).^ (listed under 0.5 mg/m3 TW A (as Ba, except barium sulfate) (listed under Barium, soluble compounds). 0.5 mg/m3 TW A (listed under Barium).0.5 mg/m3 TW A (as Ba) (listed under Barium, soluble compounds). Barium bromide, anhydrous 0.5 mg/m3 TW A (as Ba) under Barium, soluble compounds).^ (listed 0.5 mg/m3 TW A (as Ba, except barium sulfate) (listed under Barium, soluble compounds). 0.5 mg/m3 TW A (as Ba) (listed under Barium, soluble compounds). OSHA Vacated PELs: Barium bromide dihydrate: No OSHA Vacated PELs are listed for this chemical. Barium bromide, anhydrous: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Powder Appearance: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Decomposition Temperature: Not available. Solubility: Soluble. Specific Gravity/Density: 3.5800g/cm Molecular Formula: BaBr2.2H2O Molecular Weight: 333. Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Not currently available. Conditions to Avoid: Dust generation, moisture. Incompatibilities with Other Materials: Acids. Hazardous Decomposition Products: Barium oxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - Toxicological Information RTECS#: CAS# 7791-28-8 unlisted. CAS# 10553-31-8 unlisted. LD50/LC50: Not available. Not available. Carcinogenicity:

European/International Regulations

European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/22 Harmful by inhalation and if swallowed. Safety Phrases: S 28A After contact with skin, wash immediately with plenty of water . WGK (Water Danger/Protection) CAS# 7791-28-8: 1 CAS# 10553-31-8: No information available. Canada - DSL/NDSL CAS# 10553-31-8 is listed on Canada's NDSL List. Canada - WHMIS This product has a WHMIS classification of D1B. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 7791-28-8 (listed as Barium, soluble compounds) is listed on the Canadian Ingredient Disclosure List. CAS# 10553-31-8 (listed as Barium, soluble compounds) is listed on the Canadian Ingredient Disclosure List. Section 16 - Additional Information MSDS Creation Date: 9/02/ Revision #3 Date: 12/02/ The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.