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tablas de termodinamicas, Apuntes de Fisicoquímica

tablas de termodinamicas valores

Tipo: Apuntes

2021/2022

Subido el 03/11/2022

ana-garcia-0901
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Thermodynamic Data for Selected Elements and Inorganic Compounds
at 1 bar and 298 Ka
Substance Δf
H°
/
kJ mol–1 Δf
G°
/
kJ mol–1
S°
/
J K–1 mol–1
C°
p
/
J K–1 mol–1
Ag^sh0042.725.4
Ag+^aqh105.9 77.1 72.68
AgCl^sh2127.0 2109.8 96.2 56.8
AgBr^sh2100.4 296.9 107.1 52.38
AgI^sh261.8 266.3 115. 5 54. 43
AgNO3^sh2124.4 233.41 140 .9 9 3.05
Al^sh0 0 28.32 24.34
Al3+^aqh2524.7 2485 2313
AlCl3^sh2704.2 2628.8 110.67 91.8 4
Al2O3^sh21675.7 21582.3 50.9 78.99
Ar^gh00154.820.79
Ba^sh0062.528.1
Ba2+^aqh2537.6 2560.8 10
BaCl2^sh2858.6 2810.9 123.7 75.31
BaO^sh2548.0 2520.3 72.1 47.3
BaSO4^sh21473.2 21362.2 132.2 101.8
BaCO3^sh21213.2 21134.4 112.1 86.0
Br2^lh0 0 152.2 75.69
Br2^gh30.9 3.1 245.5 36.0
a Data are mostly f rom The NBS Tables of Chemical Thermodynamic Properties, D. O. Wagman
et al., J. Phys. Chem. Ref. Data 11, Supplement No. 2 ^1982h. The values for ions in aqueous
solution ^1Mh, such as Li+^aqh, are based on the convention that all the properties listed for
H+^aqh are equal to zero.
APPENDIX B
Thermodynamic Data
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Thermodynamic Data for Selected Elements and Inorganic Compounds at 1 bar and 298 K a

Substance Δ f H–°/kJ mol –1^ Δ f– G°/kJ mol –1^ S–°/J K–1^ mol –1^ C–°p/J K–1^ mol –

Ag^ s h 0 0 42.7^ 25. Ag +^ aq h 105.9^ 77.1^ 72.68^ — AgCl^ s h 2 127.0^2 109.8^ 96.2^ 56. AgBr^ s h 2 100.4^2 96.9^ 107.1^ 52. AgI^ s h 2 61.8^2 66.3^ 115.5^ 54. AgNO 3 ^ s h 2 124.4^2 33.41^ 140.9^ 93. Al^ s h 0 0 28.32^ 24. Al 3+^ aq h 2 524.7^2485 2313 — AlCl 3 ^ s h 2 704.2^2 628.8^ 110.67^ 91. Al 2 O 3 ^ s h 2 1675.7^2 1582.3^ 50.9^ 78. Ar^ g h 0 0 154.8^ 20. Ba^ s h 0 0 62.5^ 28. Ba 2+^ aq h 2 537.6^2 560.8^10 — BaCl 2 ^ s h 2 858.6^2 810.9^ 123.7^ 75. BaO^ s h 2 548.0^2 520.3^ 72.1^ 47. BaSO 4 ^ s h 2 1473.2^2 1362.2^ 132.2^ 101. BaCO 3 ^ s h 2 1213.2^2 1134.4^ 112.1^ 86. Br 2 ^ l h 0 0 152.2^ 75. Br 2 ^ g h 30.9^ 3.1^ 245.5^ 36.

a (^) Data are mostly from The NBS Tables of Chemical Thermodynamic Properties , D. O. Wagman et al., J. Phys. Chem. Ref. Data 11 , Supplement No. 2 ^ 1982 h. The values for ions in aqueous solution ^ 1 M h, such as Li+^ aq h, are based on the convention that all the properties listed for H+^ aq h are equal to zero.

A P P E N D I X B

Thermodynamic Data

Substance Δ (^) f H–°/kJ mol –1^ Δ (^) f G–°/kJ mol –1^ S–°/J K–1^ mol –1^ C–p°/J K–1^ mol – Br^ g h 111.7^ 82.4^ 175.0^ 20. Br−^ aq h 2 121.6^2 104.0^ 82.4^ — HBr^ g h 2 36.4^2 53.4^ 198.7^ 29. C^graphiteh 0 0 5.7^ 8. C^diamondh 1.90^ 2.87^ 2.4^ 6. CO^ g h 2 110.5^2 137.3^ 197.9^ 29. CO 2 ^ g h 2 393.5^2 394.4^ 213.6^ 37. CO 2 ^ aq h 2 413.8^2 386.0^121 — CO 3 2−^ aq h 2 677.1^2 527.8^2 56.9^ — HCO− 3 ^ aq h 2 692.0^2 586.8^ 91.2^ — H 2 CO 3 ^ aq h 2 698.7^2 623.1^191 — HCN^ g h 135.1^ 124.7^ 201.8^ 35. CN−^ aq h 151.6^ 172.4^ 94.1^ — Ca^ s h 0 0 41.6^ 25. Ca 2+^ aq h 2 542.8^2 553.6^2 53.1^ — CaO^ s h 2 635.6^2 604.2^ 39.8^ 42. Ca^OHh 2 ^ s h 2 986.6^2 896.8^ 83.4^ 84. CaCl 2 ^ s h 2 795.8^2 748.1^ 104.6^ 72. CaCO 3 ^calciteh 2 1206.9^2 1128.8^ 92.9^ 83. Cl 2 ^ g h 0 0 223.0^ 33. Cl^ g h 121.4^ 105.3^ 165.2^ 21. Cl−^ aq h 2 167.2^2 131.2^ 56.5^ — HCl^ g h 2 92.3^2 95.3^ 186.5^ 29. Cr^ s h 0 0 23.77^ 23. Cr 2 O 3 ^ s h 2 1139.7^2 1058.1^ 81.2^ 118. CrO 4 2−^ aq h 2 881.2^2 727.8^ 50.2^ — Cr (^2) O 7 2−^ aq h 2 1490.3^2 1301.1^ 261.9^ — Cu^ s h 0 0 33.15^ 24. Cu+^ aq h 51.9^ 50.2^226 — Cu 2+^ aq h 64.8^ 65.5^2 99.6^ — Cu 2 O^ s h 2 168.6^2 146.0^ 93.14^ 63. CuO^ s h 2 157.3^2 129.7^ 42.63^ 44.

Li+^ aq h 2 278.5^2 293.8^ 14.23^ —

NH+ 4 ^ aq h 2 132.5^2 79.3^ 113.4^ —

H 2 SO 4 ^ l h 2 814.0^2 690.0^ 156.9^ —