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UNITS 1-4: REVIEW FROM HIGH SCHOOL
UNIT 5: THERMODYNAMICS
ENERGY BASICS
Potential heat: energy an object has b/c of
its position, composition, or condition
EXOTHERMIC: change that releases heat
(e.g. combustion)
- ΔT<0, heat is released (q < 0)
Kinetic energy: energy that an object
possesses b/c of it motion
ENDOTHERMIC: change that absorbs heat
(e.g. cold pack)
- ΔT>0, heat is absorbed (q > 0)
Law of conservation of energy: energy cannot be destroyed nor created, it can only be
changed
Thermal energy: random motion of atoms and molecules (type of kinetic energy)
- Fast moving molecules
thermal energy HOT
- Slow moving molecules
thermal energy COLD
HEAT
Heat (q): transfer of thermal energy
between 2 bodies of different temperature
Heat flow:
thermal energy of one and
thermal energy of other
THERMAL EQUILIBRIUM: when 2 substances are placed in contact, thermal energy flow from
the
temperature substance to the
temperature substance until BOTH substances are at
SAME TEMPERATURE (same KE)
HEAT CAPACITY: extensive property,
amount affects it
SPECIFIC HEAT CAPACITY: intensive
property – only depends on what the
substance is, not amount
CALORIMETRY
Measures the amount of heat transferred/exchanged to or from a substance using a
calorimeter (device that measures amount of heat)
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UNITS 1-4: REVIEW FROM HIGH SCHOOL

UNIT 5: THERMODYNAMICS

ENERGY BASICS

Potential heat: energy an object has b/c of its position, composition, or condition

EXOTHERMIC : change that releases heat (e.g. combustion)

  • ΔT<0 , heat is released ( q < 0 )

Kinetic energy: energy that an object possesses b/c of it motion

ENDOTHERMIC : change that absorbs heat (e.g. cold pack)

  • ΔT>0 , heat is absorbed ( q > 0 )

Law of conservation of energy: energy cannot be destroyed nor created, it can only be changed

Thermal energy: random motion of atoms and molecules (type of kinetic energy)

  • Fast moving molecules ➡ ⬆ thermal energy ➡ HOT
  • Slow moving molecules ➡ ⬇ thermal energy ➡ COLD

HEAT

Heat (q): transfer of thermal energy between 2 bodies of different temperature

Heat flow: ⬆ thermal energy of one and ⬇ thermal energy of other

THERMAL EQUILIBRIUM: when 2 substances are placed in contact, thermal energy flow from the ⬆ temperature substance to the ⬇ temperature substance until BOTH substances are at SAME TEMPERATURE (same KE)

HEAT CAPACITY: extensive property, amount affects it

SPECIFIC HEAT CAPACITY: intensive property – only depends on what the substance is, not amount

CALORIMETRY

Measures the amount of heat transferred/exchanged to or from a substance using a calorimeter (device that measures amount of heat)

CALORIMETRY PRINCIPLES:

Types of Calorimeters

  1. Bomb Calorimeter : ○ Used for combustion reactions. ○ Measures heat transfer at constant volume. ○ Accurate for determining the energy content of fuels.
  2. Coffee Cup Calorimeter : ○ A simpler device used for reactions in solution. ○ Operates at constant pressure. ○ Often used in labs for enthalpy changes (ΔH\Delta HΔH).

ENTHALPY

H = U + PV

where:

● H: Enthalpy ● U: Internal energy ● P: Pressure ● V: Volume

Enthalpy is a state function , its value depends only on the current state of the system (defined by parameters such as pressure, temperature, and composition) and not on the path taken to reach that state. This is because U, P, and V are also state functions.

First Law of Thermodynamics:

Reversing step 2:

CO2(g) → CO(g) + 12O2(g) ΔH = +283.0 kJ

Adding:

C(s) + 12O2(g) → CO(g)

ΔH = −393.5 + 283.0 = −110.5 kJ