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chemistry chapter 3 study notes
Typology: Study notes
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Potential heat: energy an object has b/c of its position, composition, or condition
EXOTHERMIC : change that releases heat (e.g. combustion)
Kinetic energy: energy that an object possesses b/c of it motion
ENDOTHERMIC : change that absorbs heat (e.g. cold pack)
Law of conservation of energy: energy cannot be destroyed nor created, it can only be changed
Thermal energy: random motion of atoms and molecules (type of kinetic energy)
Heat (q): transfer of thermal energy between 2 bodies of different temperature
Heat flow: ⬆ thermal energy of one and ⬇ thermal energy of other
THERMAL EQUILIBRIUM: when 2 substances are placed in contact, thermal energy flow from the ⬆ temperature substance to the ⬇ temperature substance until BOTH substances are at SAME TEMPERATURE (same KE)
HEAT CAPACITY: extensive property, amount affects it
SPECIFIC HEAT CAPACITY: intensive property – only depends on what the substance is, not amount
CALORIMETRY
Measures the amount of heat transferred/exchanged to or from a substance using a calorimeter (device that measures amount of heat)
Types of Calorimeters
where:
● H: Enthalpy ● U: Internal energy ● P: Pressure ● V: Volume
Enthalpy is a state function , its value depends only on the current state of the system (defined by parameters such as pressure, temperature, and composition) and not on the path taken to reach that state. This is because U, P, and V are also state functions.
First Law of Thermodynamics:
Reversing step 2:
CO2(g) → CO(g) + 12O2(g) ΔH = +283.0 kJ
Adding:
C(s) + 12O2(g) → CO(g)
ΔH = −393.5 + 283.0 = −110.5 kJ