COordination compound, Study notes of Chemistry

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CN aybudizatien

tetalhesal

dsp'

dsp' spžd Buigonal^ bipyaanidal^ (ree)

d² sp3innex^ orbtal^ CenmfotaladaHockaladHal

6 spBd (glha mtitad anpky)0 ckalada

utuwost cuell

3d

0t: 3d5 ys!

4p

d²sp

• AmneH cobital pe

POMAaqneo

Co3+:3A

3d

nH shrong ied 2gawd

(SeL)

ys

4s

hy se^

• Inne orbital couples

take plae do aa to

Co3t:

ot: 3d

3d

P: weak fied luganle 4d

K Feagazo (uwupaide)Sp^ d Higla (^) cemples

WPl: (^) Haudu (^) Ho,DH (^) HS SPL!

fe3t: (^) 34s

gsaaal state)

3

d 2 Sp

Zn* 3dlb

4p

Sp3 (^) tetrahedeal

Ni (^) N:3J84s

N¡2t

3d

tsguave plana

• (^) imagnele

clsp

Ni2 : 3d

Us

sp

tehahelal

pasaagnele

Jn tuis cane anonia bbeing eing a^ Abrong^ iesd^ igadigand

eAeite tae^ 2ole-^ to^ Up^ grbita^ thus

Ihe spin enly magute

PHedict

em

3d

titoahecual'

Br (^) B (^) Bo

sp

#Limitatin VBT

3 does^ not^ expl^ Cus^ tle^ colae

Conpouwo

coloe cordliatio

gt does^ wot^ pred'd^

t Stabilit^ e^ co-rdimati^ on^

cempc

blw weak iea storg

Mot moke

CApIeo

ehalaedal

etact oictim whetae ataaA

ytalild pliting

a d obi^ tals)

dy'y

A lal^ Sel

na octadlaHal tadilval ied lgade appuaach^ lum A,-X, ty-y,i-^ dAuclen^ 1hisThis^ weAls^

m

aaa epuaiem^ or^ dxt-^ y^

gdz• wnile^ dy,dyz

lrel

CEYneA t to be leawe ttaa

In eqy blo^ &^ lery^ a^ d-^ subshell

+24=o =2y

-y-bo

3Ao

Augad ield

(Mypo heical) (^) dya dz x

ente

orbital oicted

odalhedsul

held

(^34) dydydM

Magnitude

uyta fitd^ lugamd^

dpsuda

Th ligasde^ lotuck^ came^ qeatex^

iya

otaeH.

pLcio Cuuia^ tngualy deteuuu^ seuie absonpuen of^ ligat^ ycempues

Lugasd

I

K NCSKEOTA<NH2 py< en <NO, < CN<co

C (^) donor>N-dono

O-cloo>Halicles

SAL 11|

d

ty

fpaig e- wu be

disps

spad

SPL

4s

dap

3d

Euien c ae

faisg

3 to 4d (^) is not possible

alaoAMet (^) taku (^) pla

pesible

U7gao (^) metalle (^) (oupoade

Cempoumdk aneing ateart

anben bend

me wetal

Bond

gsignad's

Heagnt

zeigels

R-bonded

k

T'meHyl (^) Auminium()AR

lithiwm diwnethyl cupniale Ha,ulil

K- (^) Bond ed

Zei'se '6 Salt

feunocene

t|

EAN (^) : 34

Di (^) beazee (^) homim0)

6e- don0r

elo: 24

Meia axlmyle

Co

mnw)o

Co Co

Co t

Impbrt aul Point

Niu:3d

3d (^) 4s (^) 4P^ is^ benane^ as^ ghhong

d'sp

Co) (^) alwys (^) fon innet (^) orbi (^) tal (^) cmples es

d'sp

3t (^) mawny (^) Jomsiner

obital omplenes except

(nnee (^) ooi (^) tol (^) capleo 3

(d'sp

Arnmonía at as

fe2 4 Mn2t

dtsps

dhrong ield byaud except ait,

mnt: (^) 3ds (^) spd

outex-obital

Higlh spin

6mpces.