Coordination Compound Notes, Study notes of Chemistry

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A TT ETT SRG TOR LAT LEAN SER EARLIER ae nme Coondindiian Compounds Paes ondemmaton compounds te. spittin Comporends » — Mm a 20 bi Coemp ne made by epee flce on amore srimple stable Qunds ‘ ¢ : a bbe 7 2m “stim ple Molecular CsFacheban Crcee ? preperthoms a & ew a aie apenale ereysTals of Mew substamocs cay tepanale These Mubstances arco Terme as omelecular ar addi ae ae ae ae , LTtOw © © | euble sale @Q Cooncemals satp’. > (way), nigh RC beng SOy 4 cSt Fe $0, + Heo |? Ken + Fe lend, + HO + $0477) ' wv y Fort $0y>~ ! (kt ren) | (Ferg CN ©) ad aie 6 Coury x i Mohn Salk sfeRitiy) & -Fe 0, [24,0 ] Double gali- fusnet valor desselve JTat Thes att do mal- 7 : NH? Fe>* 92 ane , produce cnO ah Aywoces cof Preocleece oe : Because thd w' a Complex ? complet, dontsed sen usaten Galh . PSF Lobes iE sdondte 3 } fF Loges lf dderdity ; | ky Epectngy ee ie + Cre cen y Comptey salt 4 : Lay ® | fon re | Qonching Oc Complex i There & a cooncenale- | ‘bond formation b/w cw O & Fe2t ly Do ast oause completely ‘ ! > ~2 Ganplex ton retain Elf motu co Naittrsce calm. ET SE TATE © Ligand - > Dener Grcup tm Ccexdimats bond formation . Typ « of Ligand . © om the base of change . @ Newnal — Co, no, Nts ete . 6 Cotton —» No” of © Amen — ON- ete. @ om The bare of mo Coe - of Coondemale” chancl forcmed by one Aigand wuth teargle eentrnal atorn [Wenteeity J ® Momodentale an UncdenPité PSiingle Coendémalc ‘bonof foremeot sey. ogandl » Naming of Ligand -- © Negative [ Unédentati J 2- FES "Sticona ( Slorido)'2 C1 > Clore ( Chlorede) Br ~> @rommo -C-teresiractle) T° Sod (Sodvde) on® > Ayolreorwo No > Nitrite: no! > Netrato. © Poly dential s —2 er emors Coondemale bonof egret sty Ager : Coe” Ws Canbenats S077 Sulphato 502 ~~ Sulphito 3 S° Sut heifo - C(NO > Cyano roa 7 Oxo sy? es Shio Cyanato < Dar eoampler sall- both wom (cation y amiom) cam be Complex vom [ cotn tae J*™ [rien Cen & 4 (7 Coordimale connplex Cam be meccTeeat Nc(Co dy | : Coordinate Compouno S 0) Z Ope” pnp Ligord done atoms £0; ametecule = : & eae Bome si ) Courtere vom —» Kus [re 0] Nom - tonitceb le - Pree 2 f 2 Cooredeinale “apliae ee : "— Wentreal anetal 7 Wir sbolanee \oo fi PA rere ? Cooredeimetioen No» eke ind) of Ligand: . the Chorege Poreticepale” sn of coo reds martin Ceoredimate ‘bond Spherte- fo rematiom Acetpton aterm (accept 7 pare won FED. ‘ond ] ~ NV Jomisalion = 4p. + CrésnyeJ eas oat ponindiionm Spher@. sg t. 49 749 ‘[G 0h) hy Somitstlon ei, Te 4 / ea? “Cereal a ~ Aaa Complex @ Cen) 1, wie As shal - Fe, [Fe alae monet i Sl + % Crecene] - : rent ab Oy SEN ITNGY Sino Counters : S fn» rein a Bw 2. é @® Aruidentate ~» Weutval) “~_eorv’” a Ni CHe 1 \ ch ONNA W35 7 Ay J CH, ANH, Orettylenc steiaméne Aanidentate . Ligands es | | | lexadlentale : - neon > 0 F ac) cn we AH 2-0 > “TN | = cH, 2-7 SE 9? 0 0° at be —cH, —c—©., oY boys ~0? CH, “G 2 peor” ; (Ethylene oltaomime Petra acetals ) — evostly uh hexadentale bub Jf Cam the Aefradentalé alse . \ > when mone dentale Ligamd a ” on mone | : demore atoan - ; 2G cam spon Coondimal bom fem 2 defhercnté atoms - : G r 2) ag) ea i oop “ge O No, ® [en 7° ay wat, aes =, Sonn 20a SING €&N se Nc® 4 Yo : oa andro Gyane Ssocyano : attro (0) nt’ tye) 0) (seu JO Se ted eee & yeg® J feceyanat 0 S50 thiocyanate : QO 9 olomen (?. + then, 2 Oond efowmed ‘bles. Lyand ane N ty ——_ Cn 0 cot ametal voy olomaliem @r sharcag of “en pase by Ligand - ® 9% demon, acceptor . > dapand Sanit ee pat AS cenitrea we Kg ank boarding cefot &’ forum 9-bomd -bul- also Orebet/ al MASSE oy am ACR e broom 268 arefok em ® L whe amIebomdemg amelecelor arbrtof G9 - Co & form re homed - Lhese ty pe . NO i \eeaett plo® vay: of ey amds ance, Rap crt 0s TC Qe} y ig amd wohe'ch aceeply e” throumh_ - \ PQ) @Bomd foremed vom _ (©) we -domon : - ; 4 sites hasnt Che ; _- - rN ado H 2 PE = Aegan demab- a Bhat t cent cal anh ex Ce ae oA “- > Atal me of ngond Wiatt®: bonid fant by COrTreal coral ti th ras ‘contd 5° i \ aids Cong dws ka — “of ano a tyes sentra ex bie ® nNednats- —_— cn, - Wy, fe baer Ethylene -deameme H2— Nu 2 v on Ethane ~ 4 22 - dtaméne Cen) CNG Syomamedrefea| rs | 7 ‘ Bidentale . ‘i WZ 2,2 diy resol f (dey) e CAA) on (eB) Ortho heh olims, CPA) Negative :- © Ne Ie: Cr Oy” - Tat Paty 4 . = # eae ve onatato (ox) > Sym am gfreeenl bitferdale Coo- (aa) ‘ clit © HaN= tte C00 > Giyerate coly) yeni a ON e) CH, —C=N-64 Unsyarem hurcad = ~ brdlentalr mt Ha “Ae © ©) CHy as / > acdc (a eety La eefonate) CHS ~Nc-o ; 7 Ay @® CrrysTot Feld Theo ny (cFr) is di” the 1 they counparce coo rdimalé tonplex with Some Gmpound. 8 Jomie Compeund cation Sannounded tucth spot fe no 0+ anton amef Véee venta Coserech'natcen) mo) same wohy é eoondimate coanpter anchaf Surnoundect * astth specif mo- of jor . a fe) Nac 34 ct f ; niu | r ae [eo (us), J a 3! = eee} pee or “ De tg. x Na ious o wo bon > Bef: Ai ce al aie - 8 a - @ ! = a i oy Co {a | \ ni ae ieee TNH ¢ NUy » - y Postelates 6 CET at $ es ei ) : : ey, ) & Pune hed rotate forcce of attuadon spreesenl- bits niedfit anil wae ) & hey asseeme Aigarol as Sperm charge ( ckpole - ©) Metat Aas vacaml- orbital - » Shape...of enkital 6... Jaheste Aaa te abwadtls 18 ) OM tty ne oo he _ dx » dx ro . doo 1X82 lye, Lobes. presull aCe Cie ZN Onclere an the base of dener Oem 5 _ Halogen e Oney gen < Netragen < Carben : OHI" cow, Co, EN RRR BR 0 iy < rncon CO Weak Fit Senter anedtale Shreaveg Feb. Chey stot _Reld Stabitesing energy 7 Octahednal (eld « o v F 5 eremula CFSe = [-o4m +0.6m¢q [40 #XP tw : share: Neog asd meg ane mumbear as egy wm tog asnol °F orebttals Mr sate and Ay ere CESE fort octaheclecal cormpler “x” Mepresenl{ the mo- 6 «Peetran purs & Pu anean paring Gi) N/a 4,

P, Pho 4th en , wk Beconws amore senarg efcally sfowe ureable rfore 4th e- Le wceupy al— toy Config uraléom tog 4eg® . ey onds asherch eprreclice thes Ckheck ar0 known as Arce sfieltol ligands we

Coondimation Compler produce colour vheca ase of (a) Que Ie d-d cheamsthom 2 — oy (Hagher omegy) (4. ) % al! — t tog (Lowen enersoy ) Fal fe) tog fv > Che d-d Aromstom dake: place fron vbr ty to by ¢ DA & al? Aloe mo ded dreamictom - %~ VIBGY OR , . : Ar , Et , vd ? eth te . C.F.) - w/4 conmplex obserehs lowe -emercpy Coleg a) them thoy Aeboase — Aegh omega y { Low A) amd vdeo versa - Goapeeh} FLD : y Absonb & Sepp ear ; SP ae ; v on L (Low Aa) Geto ws aS Red Lyresen Oreqnge : uc gE . Theewes ef “Coorecliinnlé Complex formahon — Q © Valence Bond Theory i- a : @ Mefal. provide. vacanr srbetal Ame legamd. provede ebecteeon parr for eoondimale .Bomd sfertmalion ' = are © Comtuat amdfal —» Acceptor atoomgy and ale ack ag Lewoes a otf © digand >" Domor elon ame also acls ‘as bases wg. 3 2 Now = Steg? of V0 -T PEt explains the. coorde mate | Coanples formal com Vanna 4 >” nr __ Yeoametiay % Cormaplex or ~ op? + Uetnakednal - $p? d* —> oclaredrcal + j olsp™ ohh bguane «planar ete + ' x * D reasback Jt foils AF expla — @ “Stabilety of cocmpler - © Colours amd elechrte nic’ Spedra ‘ © demen amd outer otbetat coanplex - 8 eq = [Pe (en) > Cr Jt, - 3 De’ Chl robes C Oy lemedlcivmsine), pl inti Cty) Al, < (§) When am one than ome type of Lg amds ane posse! wn the. bese ; Coanplex y the the keg amds are mamed 2%n atphab chieal areeler « q) Afler cmarméong. of Ligands the eunfreat om us Lo 42 mame followed by ile coed ™ sta tn Rocmam' member Con brackels Cas pu Jur ac) amarok os tf the, Ce ipAeT. ore inreonesi, a cohomi'e tormplex vom then the ° Aunt nat rel ol fon fs AS fhe mame os £6 4 4 Ahe eoanplex prorwldles améome'e eonmpler tom them the mame of central. amen fom. ands we'th ba” : wax 1b &y - (NAY), lout, J mS toni oooaen? clePaachlocecuprest wn Pee trol . Uh) A fon ges of net ak om , ameoen which vow the euta sphere w do de manned - RBs 3 o> Asad a0 7 Y C69 ue be Change Treams fer 6/4 neta & cbyand Wise Vita cee are y : ‘ \ cLeametodeon “of CPT va Ane (1) & Considers omley the ametal om d= ermal amél geves gia eomstderalrz oF all Le there pmefal enbetab (such a1 5, Pp,» by amd Pe wbedels) 2) Se & wumable: Lé vaceb uit sativfactorely ae ie salative strength 7 Ligand: Bon & | ic Ge A psc mo explemation Qs, Me oly lz0 6 & Streemng ere i; tham OM Ten, the / (spectrochemtal Berceds , ay : C)Aie e thes Neots bond) bias ametal: amol ayer pe purely some - St: gs mo ACcoun & om the paidly segvaternt- alike of gihetal gama on ds 3 i eR Neh ysT dt ‘ , rinks es a. fe CH) CET cam’ econ fore ca = boiling sia Cownple nes - a bees Wugese wt Tahn Detlere Du'stonteoar tre : hedeal geome rl ? Que le umsyam mebnecal feueng of e- , oles foreteed octahedn fil reecluee - ni _pumayememtenced ~ do atl nig spin) , of 7 (Low spin coanptex ) ® d° oleroe™ fetter mg of e-, bo 2b se ectereachiom ligand well mel wme from all Ld 60 Cl- preodkrce defected octahedral + # Metal Corbomyl Compounds 3 - &) Sy mercgee tooending 23 Cos BN ) Not. A olo more Be sxe te Get) . ‘s ‘ jasent antcrorderl ocibeet st We 4 Nole ? O More the sy meceg te ~bendleing amore the Stabile a 5 of Complex ’ c re) bshen 0. Seale en a “ep te anteboandsng onbetale Q bond forenud y . omate - \ as #4 ng. om of e by Co decrease amd bord Len Ahe Ligand oma Langth tion Romd Oreclere: bla: blw C-6 unewue & Bomd energy b/r i C—-0 dewrooss - ® More the —ve change @2 gmefal mone fhe rt ed : OMON- Pa eee a ae ae a : = Nepales. vy Qonds, Nol © damen enbitel Connplex:— 9 when Car eidd sperilP ye “Pena oe Cn —& eefenmosh het) 9 ui case of avd’, Aid? , They eM, preasence ™m apemples Pe se - — ee a oe . Pal ' \ y, ‘ VOR Ss © [Fe Cony J" @ O.N-ot Fe = Fe + 6(-1) =-4Y- G Bees OR Pe he Fair gee © gerd ON > §.F.L ® CFSE oi