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Some topics for Process Design Practice course are Mass integration, Advanced column design, Physical property prediction, Process risk assessment and Integration of design and control. This lecture includes: Process Safety and Design , Importance of Process Safety, Recent Incidents, Process Safety Terminology, Process Hazard Analysis, Hazard Vs. Risk, Risk Assessment Example, Mitigating Process Risk, Layer of Protection Analysis, Lopa
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The safety record of the chemical process industry isthe responsibility of all of us in the profession.
-^
Process
safety
is^
important
for
employees,
the
environment, the general public, and it’s the law.
-^
As
process
design
engineers
we
are
tasked
with
reducing the risk of operating a chemical manufacturingprocess to a level acceptable to employees, regulatoryauthorities, insurance underwriters and the communityat large.
-^
Recent
chemical
plant
disasters
underscore
the
importance of this point in terms of both human andfinancial losses.
is^
a^
measure
of
the
severity
of
the
consequences
of
a
catastrophic
failure
of
a
given
process
or
system,
regardless
of
the
likelihood
and
without considering safeguards.
-^
is the combination of both the severity of the worst
case
consequence
and
the
likelihood
of
the
initiating cause occurring.
-^
In short, for an
, we have little
influence on the
, but through the application
of safeguards, we can reduce the
of operating
the process.
Process
Hazard
Analysis
is
a
technique
for
determining the RISK of operating a process or unitoperation.
-^
PHAs
are
required
by
law
for
process
handling
threshhold quantities for certain listed Highly HazardousChemicals (HHC) or flammables.
-^
Approved techniques for conducting PHAs:•^
HAZOP (Hazard and Operability)
-^
What If?
-^
FMEA (Failure Mode and Effects Analysis)
-^
In general, a PHA is conducted as a series of facilitated,team brainstorming sessions to systematically analyzethe process.
The operating risk is determined by the PHA using anappropriate Risk Assessment Methodology.
-^
This
risk
is^
mitigated
through
the
application
of
safeguards that reduce the risk to an acceptable level.
Process Risk
InherentRisk
OperatingSafeguards
Level ofAcceptableOperating Risk
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Core Process1st Layer ofProtection 2nd Layer ofProtection 3rd Layer ofProtection
Each layer must be: Independent;Effective; Reliable; Auditable.
Inherent safety is a concept based on eliminating thecauses and/or reducing the consequences of potentialprocess upsets.
-^
Inherently Safe Process Design is a technique appliedduring the conceptual phase of process design.
-^
Inherently Safe Process Design targets the
rather than reducing the
after the fact.
This
technique
is
based
on
making
inherently
safer
design choices at a point in the process developmentwhere the engineer has the most influence on the finaldesign.
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Inherently safe process design can be grouped into 5categories
-^
Each of these inherently safer design choices is appliedin the conceptual phase of development.
1
Intensification
Continuous reactor vs. batch reactor
2
Substitution
Change of feedstock
3
Attenuation
Alternate technology
4
Limitation of effects
Minimization of storage volume
5
Simplification
Gravity flow vs. pumping
Category
Example
Sample Risk Assessment using What If? Methodology
-^
Consider what types of safeguards would be required tomitigate the Process Risk due to these scenarios. What If…?
Initiating Cause
Consequence
1.^ There is higherpressure in theEntrainmentVessel?
1.1^ External fire in theprocess area.
1.1^ Potential increased temperature and pressure leading topossible vessel leak or rupture. Potential release offlammable material to the atmosphere. Potential personnelinjury due to exposure.
1.2^ Pressure regulator forinert gas pad fails open.
1.2^ Potential for vessel pressure to increase up to the inert gassupply pressure. Potential vessel leak or rupture leading torelease of flammable material to the atmosphere. Potentialpersonnel injury due to exposure.
2.^ There is higherlevel in theEntrainerVessel?
2.1^ Vessel level transmitterfails and indicates lowerthan actual volume.
2.1^ Potential to overfill vessel with cyclohexane. Potential toflood vent line with liquid leading to flammable liquidreaching the vent gas incinerator. Potential to overwhelmincinerator leading to possible explosion. Potentialpersonnel injury due to exposure.
AzeotropeColumn
Pervaporation
Unit
SolventColumn
1
2
3
4
Stream s: 1 Solvent Feed2 Azeotrope3 Waste Water4 Solvent Rich Phase5 Water Rich Phase6 Recovered Solvent
5
6
Based on this risk comparison, it is clear that multipleindependent
protection
layers
would
be
required
to
mitigate the operating risk of the traditional process.
-^
This risk can be reduced by designing an inherentlysafer, ie, less hazardous process.
-^
Although
a
complete
economic
analysis
would
be
required, this example has illustrated that the need forindependent
protection
layers
is^
reduced
in^
the
inherently safer process design.
Clearly, process safety is a critical component of processdesign.
In
industry,
no
process
is
put
into
service
without a comprehensive risk assessment.
-^
It^
is^
important
to
realize
that
the
management
of
operating risk is the key focus of process safety.
As
design engineers, we have responsibility for and themost influence on the overall hazard of a process.
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