Reaction Kinetics notes, Lecture notes of Chemistry

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2025/2026

Available from 05/06/2026

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REACTION KINETICS
Second Order
Odes of reaction Rate of reaction
Zero order directly
proportional
to squat
Rate of reaction is independent Rate of conc
of conc of reactants acone Rate A
Rate Acone Rate KA
Rate KARate K
Time
Rate
First Order Rate Conc
Rate of reaction is directly
proportion to conc of Acone a
cone Cone
Rate ARate KLA Time Time
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REACTION KINETICS

Second Order

Odes of reaction Rate of reaction Zero (^) order directly proportionalto squat Rate of reaction is independent Rate of conc of conc of reactants a cone Rate (^) A Rate A cone

Rate K A

Rate K^ A Rate K Time Rate First Order Rate Conc Rate of reaction is directly proportion to (^) conc of

A

cone a cone Cone Rate (^) A Rate KLA Time Time

Catalysis

Half Life

Homogenous catalysis Time (^) taken in (^) a reaction

for

conc to

half ty^

When reactants (^) and

cataclysts

have the

same

phase

conc tin (^) Heterogenous cataclysis 1 ˢᵗ

ty

2 ⁿ

ty

When (^) reactants and time

catalysts

have

different In conc^ Time^ Graphs (^) phases zero (^) order 1 ˢᵗ t^ y 2nd

tyz ty

decrease First order 1 ˢᵗ^

ty

2nd tya ty^ constant Undergoes diffusion

Second order 1 ˢᵗ^ t^

y

2nd ty t y increases (^) ad soo ption reaction desorption then diffusion Formula

for

1st order reaction K awayfrom surface Adsorption Old bonds breaking

Desorption

New bonds form