Solid State Nanoelectronics - Homework 8 Solved | ELEG 667, Assignments of Electrical and Electronics Engineering

Material Type: Assignment; Class: ELECTRIC POWER II; Subject: Electrical Engineering; University: University of Delaware; Term: Fall 2005;

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ELEG 667–016; MSEG-667-016 - Solid State Nanoelectronics – Fall 2005
Homework #8 - due Tuesday, 22 November 2005, in class
1. Carbon Nanotube Structure: Derive the expressions for the unit vectors of graphene (unrolled
nanotube) a1, a2, in terms of the Cartesian unit vectors x^, y^. (a) Using trigonometry, show your
calculations for the numerical factors a and b (e.g. ½ or whatever) in terms of the length of the
carbon-carbon bond length, ao. (b) sketch and indicate the unit cell in real space, which is the
parallelogram spanned by a1, and a2. Hint, consider the figures below.
2. Carbon Nanotube Dispersion: Consider the dispersion relation for graphene:
W(kx, ky) = ± γo[1+4cos(3kxa/2) cos(kya/2) + 4cos2(kya/2)]½ ,
following the notation in Waser, where a = 3ao is the length of the unit vector ai, and ao is the
length of the carbon-carbon bond (0.142 nm). Note that this “a” differs from the convention used
above in question 1. (a) Find the six Fermi level conduction points in k-space (which are the
corners of the hexagonal Brillouin zone below) by solving for the k values where W(kx, ky) = 0. (b)
On the hexagonal Brillouin zone, sketch and label the coordinates of these 6 points in terms of a, or
ao .
Hint: in the dispersion relation first let kx = 0 and solve for the corner points along ky; and then let
3kxa/2 = π, and get the corners with kx 0. This approach makes it easier to factor the dispersion
terms under the root as a perfect square. Then take the square root and solve for kx,y.
ky
kx
3. Carbon Nanotube Metallic condition: Show that the condition for metallic conductivity of
chiral nanotubes: 2n1 + n2 = 3q, where q is an integer, can be obtained by substituting the k vector
of one of the corner points of the Brillouin zone into the periodic boundary condition: Ch ·k =
2πm, where Ch = n1 a1 + n2 a2 is the chiral vector, and m is an integer. (Hint: use vector coordinates
with respect to x and y, and a zone boundary point that has both x and y components).
Homework assignments will appear on the web at:
http://www.ece.udel.edu/~kolodzey/courses/eleg667_016f05.html
Note: On each submission, give your name, due date, assignment number and course number.

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ELEG 667–016; MSEG-667-016 - Solid State Nanoelectronics – Fall 2005

Homework #8 - due Tuesday, 22 November 2005, in class

  1. Carbon Nanotube Structure: Derive the expressions for the unit vectors of graphene (unrolled nanotube) a 1 , a2 , in terms of the Cartesian unit vectors x^ , y^. (a) Using trigonometry, show your calculations for the numerical factors a and b (e.g. ½ or whatever) in terms of the length of the carbon-carbon bond length, ao. (b) sketch and indicate the unit cell in real space, which is the parallelogram spanned by a 1 , and a2. Hint, consider the figures below.
  2. Carbon Nanotube Dispersion: Consider the dispersion relation for graphene:

W(kx, ky) = ± γo[1+4cos(√3kx a /2) cos(k (^) y a /2) + 4cos 2 (ky a /2)] ½^ ,

following the notation in Waser, where a = √ 3 ao is the length of the unit vector ai , and ao is the length of the carbon-carbon bond (0.142 nm). Note that this “ a ” differs from the convention used above in question 1. (a) Find the six Fermi level conduction points in k-space (which are the corners of the hexagonal Brillouin zone below) by solving for the k values where W(kx, k (^) y) = 0. (b) On the hexagonal Brillouin zone, sketch and label the coordinates of these 6 points in terms of a , or ao. Hint: in the dispersion relation first let kx = 0 and solve for the corner points along k (^) y; and then let √3k (^) xa/2 = π, and get the corners with kx ≠ 0. This approach makes it easier to factor the dispersion terms under the root as a perfect square. Then take the square root and solve for k (^) x,y. k (^) y

kx

  1. Carbon Nanotube Metallic condition: Show that the condition for metallic conductivity of chiral nanotubes: 2n 1 + n 2 = 3q, where q is an integer, can be obtained by substituting the k vector of one of the corner points of the Brillouin zone into the periodic boundary condition: Ch • · k = 2 πm, where Ch = n 1 a1 + n 2 a2 is the chiral vector, and m is an integer. (Hint: use vector coordinates with respect to x and y, and a zone boundary point that has both x and y components).

Homework assignments will appear on the web at: http://www.ece.udel.edu/~kolodzey/courses/eleg667_016f05.html Note: On each submission, give your name, due date, assignment number and course number.