Cálculo de la Constante de Equilibrio
Jorge Andrés Pérez 20121001795
Constantes
In[1]:= Na :=6.022 *10 ^ (23)
In[2]:= Uma :=1 660 538 921 *10 ^ (- 27)
In[3]:= mh2 :=0.002 /Na
In[4]:= mo2 :=0.032 /Na
In[5]:= mh2o :=0.018 /Na
In[6]:= kb :=1.3806488 *10 ^ (-23)
In[7]:= h :=6.62606896 *10 ^ (-34)
In[8]:= R :=8.314472
In[9]:= σh2 :=2; σo2 :=2;
In[10]:= θh2 :=5977.7; θo2 :=2238.9;
In[11]:= θh2o := {2290, 5160, 5360}
In[12]:= θ:= {40.1, 20.9, 13.4}
In[13]:= Dh2 :=103.25 *4184
In[14]:= Do2 :=117.97 *4184
In[15]:= Dh2o :=219.3 *4184
In[16]:= P :=101.3 *10 ^ 3
Funciones de Partición
In[17]:= qh2[T_] = 2πmh2 kb T
h ^ 2
3/2T
σh2 85.35
1
(1-Exp[-θh2 /T]) Exp[Dh2 / (R T)];
In[18]:= qo2[T_] = 2πmo2 kb T
h ^ 2
3/2T
σo2 *2.07
3
(1-Exp[-θo2 /T]) Exp[Do2 / (R T)];
In[19]:= qh2o[T_] = 2πmh2o kb T
h ^ 2
3/2T^ 3
θ[[1]] θ[[2]] θ[[3]]
Sqrt[π]/2
(1-Exp[-θh2o[[1]] / T])
1
(1-Exp[-θh2o[[2]] / T])
1
(1-Exp[-θh2o[[3]] / T]) Exp[Dh2o / (R T)];
