Phase Changes in Matter: A Comprehensive Guide with Exercises, Exercises of Chemistry

exothermic change, the system releases energy to its surroundings. Freezing is an example of an exothermic change. Charactaristics of Phase Changes ...

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3.3 Phase Changes
A large iceberg contains enough fresh water to supply
millions of people with water for a year. As it moves
into warmer areas, the ice changes to liquid water and
eventually disappears. What happens when a
substance changes from one phase to another?
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A large iceberg contains enough fresh water to supply millions of people with water for a year. As it moves into warmer areas, the ice changes to liquid water and eventually disappears. What happens when a substance changes from one phase to another?

Melting, freezing, vaporization, condensation, sublimation, and deposition are six common phase changes.

When at least two states of the same substance are present, scientists describe each different state as a phase. A phase change is the reversible physical change that occurs when a substance changes from one state of matter to another.

Charactaristics of Phase Changes

The temperature of a substance does not change during a phase change.

One way to recognize a phase change is by measuring the temperature of a substance as it is heated or cooled.

Charactaristics of Phase Changes

Temperature and Phase Changes

This is a graph of the data collected when a solid piece of naphthalene is slowly heated. The temperature of the naphthalene rises until it reaches 80°C. The temperature remains at 80°C, the melting point of naphthalene, until melting is complete.

Charactaristics of Phase Changes

Energy is either absorbed or released during a phase change.

During a phase change, energy is transferred between a substance and its surroundings. The direction of the transfer depends on the type of phase change.

Charactaristics of Phase Changes

Energy and Phase Changes

This ice sculpture of a dog sled was carved at a winter fair in Fairbanks, Alaska. The ice sculpture will start to melt if the temperature rises above 0°C or sunlight shines directly on the ice.

Charactaristics of Phase Changes

Energy released as ice forms on these strawberry plants keeps the plants from freezing at temperatures slightly below 0°C

Charactaristics of Phase Changes

One gram of water releases 334 joules of energy to its surroundings as it freezes, the same amount of energy that is absorbed when one gram of ice melts. As water freezes, it releases heat. The flow of heat slows the drop in temperature and helps protect the crops from damage. During an exothermic change, the system releases energy to its surroundings. Freezing is an example of an exothermic change.

Charactaristics of Phase Changes

Melting Each water molecule contains two hydrogen atoms and one oxygen atom. In ice, attractions between water molecules keep the molecules in fixed positions. Any energy gained by the water after a phase change increases the average kinetic energy of the molecules, and the temperature rises.

Melting and Freezing

When ice cubes are removed from a freezer, heat flows from the air to the ice.

  • As the ice gains energy, the molecules vibrate more quickly.
  • At the melting point of water, 0°C, some molecules gain enough energy to overcome the attractions and move from their fixed positions.
  • When all the molecules have enough energy to move, melting is complete.

Melting and Freezing

When liquid water is placed in a freezer, energy flows from the water to the air in the freezer, and the water cools.

  • As the average kinetic energy of its molecules decreases, they move more slowly.
  • At the freezing point of water, some molecules move slowly enough for the attractions between molecules to have an effect.
  • When all the molecules have been drawn into an orderly arrangement, freezing is complete.

Melting and Freezing

The phase change in which a substance changes from a liquid into a gas is vaporization.

  • Vaporization is an endothermic process.
  • One gram of water gains 2261 joules of energy when it vaporizes.
  • This amount of energy is the heat of vaporization for water. The heat of vaporization varies from substance to substance.

Vaporization and Condensation

In a refrigerator, a pair of phase changes keeps the food cold.

Vaporization and Condensation

Evaporator

Compressor

Condenser

Energy released to surroundings

Energy removed from food compartment

Evaporation After a rain shower on a sunny, warm day, you may notice puddles of water. After a few hours, the puddles may be gone due to evaporation. Evaporation changes a substance from a liquid to a gas at temperatures below the substance’s boiling point.

Vaporization and Condensation