Download Safety Data Sheet for Acetyl Bromide: Uses, Classification, and Handling and more Study notes English in PDF only on Docsity!
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/ Date of issue: 11/14/2019 Version: 1.
EN (English) 1/
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Substance
Substance name : Acetyl bromide
EC-No. : 208-061-
CAS-No. : 506-96-
Product code : 10636571
Formula : C2H3BrO
Product group : Raw material
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Laboratory use,Industrial use,Professional use
Industrial/Professional use spec : For professional use only
Use of the substance/mixture : For analytical purposes Scientific research and development Not for human consumption or veterinary purposes.
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Supplier
Scafell Organics Molekula Ltd Lingfield Way Darlington - England T +44 (0) 1949 823777 / +44 (0) 7590 545705 [email protected] / [email protected] - www.molekula.com
1.4. Emergency telephone number
Emergency number : +44 (0) 7590 545705
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation, Category 1C H
Hazardous to the aquatic environment — Chronic Hazard, Category 3 H
Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS
Signal word (CLP) : Danger
Hazard statements (CLP) : H314 - Causes severe skin burns and eye damage. H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P223 - Do not allow contact with water. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
EUH-statements : EUH014 - Reacts violently with water.
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/
SECTION 3: Composition/information on ingredients
3.1. Substances
Name Product identifier %
Acetyl bromide (CAS-No.) 506-96- (EC-No.) 208-061-
Full text of H-statements: see section 16
3.2. Mixtures
Not applicable
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : If possible show this sheet, if not available show packaging or label. Never give anything by mouth to an unconscious person. Do not leave affected person unattended.
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Give oxygen or artificial respiration if necessary. If breathing difficulties persist : Get medical advice/attention.
First-aid measures after skin contact : After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water. Do not remove clothing if it sticks to the skin. If irritation persists, consult a doctor.
First-aid measures after eye contact : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. Do not induce vomiting. Get medical advice/attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : Material is destructive to tissue of the mucuous membranes and upper respiratory tract. Cough, shortness of breath, headache, nausea. Burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. May be harmful if inhaled.
Symptoms/effects after skin contact : Causes severe burns. May produce skin irritation, blistering, ulcers, and deep scarring. Cracking of the skin. Redness, pain.
Symptoms/effects after eye contact : Causes serious eye burns. redness, itching, tears. stinging. Blurred vision. More severe symptoms are also possible.
Symptoms/effects after ingestion : Burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Symptoms of ingestion include drowsiness, weakness, headache, dizziness, nausea, vomiting. More severe symptoms are also possible.
4.3. Indication of any immediate medical attention and special treatment needed
May cause severe chemical burns to skin and cornea. Suitable first-aid treatment should be immediately available. Seek medical advice before
using product.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Dry powder. Sand.
Unsuitable extinguishing media : Do NOT use water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of fire : Carbon oxides (CO, CO2). hydrogen bromide.
5.3. Advice for firefighters
Precautionary measures fire : Keep container tightly closed and away from heat, sparks and flame. Keep away from combustible materials.
Firefighting instructions : Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Other information : Warn all persons of toxic hazard.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Isolate from fire, if possible, without unnecessary risk. Do not breathe gas, fumes, vapour or spray. No flames, no sparks. Eliminate all sources of ignition.
6.1.1. For non-emergency personnel
Protective equipment : Wear recommended personal protective equipment.
Emergency procedures : Evacuate unnecessary personnel. Mark out the contaminated area with signs and prevent access to unauthorized personnel. Do not touch or walk on the spilled product. Avoid contact with skin, eyes and clothing.
Measures in case of dust release : Shelter from vapours by keeping upwind. Ventilate the area thoroughly, especially low lying areas (basements, workpits etc).
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/
Skin and body protection:
Emergency safety showers should be available in the immediate vicinity of any potential exposure. Keep suitable chemically resistant protective clothing readily available for emergency use
Type Standard
Total impervious protective suits, gloves, and boots must be worn to prevent any contact with the product
EN 14605
Respiratory protection:
Keep self contained breathing apparatus readily available for emergency use. Where exposure through inhalation may occur from use, respiratory protection equipment is recommended
Device Filter type Condition Standard
Air-Purifying Respirator (APR), reusable
ABEK Moist condition, Mist formation, Protection for Liquid particles, Vapour protection
EN 14387
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear.
Molecular mass : 122.95 g/mol
Colour : Colourless. light yellow. light brown.
Odour : No data available.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -96 °C lit.
Freezing point : No data available
Boiling point : 75 - 77 °C lit.
Flash point : 110 °C closed cup.
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Non flammable.
Vapour pressure : 122.9 hPa at 25 °C
Relative vapour density at 20 °C : No data available
Relative density : 1.663 g/cm
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Protect from sunlight. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Light sensitive. Moisture.
Water, humidity.
10.5. Incompatible materials
Strong oxidizers. Strong bases. alcohols.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/
10.6. Hazardous decomposition products
No hazardous decomposition products known at room temperature. Thermal decomposition generates : Carbon oxides (CO, CO2). hydrogen
bromide.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Additional information : Based on available data, the classification criteria are not met
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Additional information : Based on available data, the classification criteria are not met
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Reproductive toxicity : Not classified
Additional information : Based on available data, the classification criteria are not met
STOT-single exposure : Not classified
Additional information : Based on available data, the classification criteria are not met
STOT-repeated exposure : Not classified
Additional information : Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential adverse human health effects and symptoms
: Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
12.1. Toxicity
Hazardous to the aquatic environment, short-term (acute)
: Not classified
Hazardous to the aquatic environment, long-term (chronic)
: Harmful to aquatic life with long lasting effects.
Acetyl bromide (506-96-7)
LC50 fish 1 40.6 mg/l Pimephales promelas (fathead minnow) 96hr
12.2. Persistence and degradability
Acetyl bromide (506-96-7)
Persistence and degradability No data available.
12.3. Bioaccumulative potential
Acetyl bromide (506-96-7)
Bioaccumulative potential No data available.
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
Acetyl bromide (506-96-7)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6. Other adverse effects
Additional information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/
Properties and observations (IMDG) : Colourless liquid.Reacts violently with water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Vapour irritates mucous membranes.
Air transport
PCA Excepted quantities (IATA) : E
PCA Limited quantities (IATA) : Y
PCA limited quantity max net quantity (IATA) : 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
ERG code (IATA) : 8L
Inland waterway transport
Classification code (ADN) : C
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
Rail transport
Classification code (RID) : C
Limited quantities (RID) : 1L
Excepted quantities (RID) : E
Packing instructions (RID) : P001, IBC
Mixed packing provisions (RID) : MP
Portable tank and bulk container instructions (RID) : T
Portable tank and bulk container special provisions (RID)
: TP
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Acetyl bromide is not on the REACH Candidate List
Directive 2012/18/EU (SEVESO III)
15.1.2. National regulations
No additional information available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out for the substance or the mixture by the supplier
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.
Full text of H- and EUH-statements:
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
Skin Corr. 1C Skin corrosion/irritation, Category 1C
H314 Causes severe skin burns and eye damage.
H412 Harmful to aquatic life with long lasting effects.
EUH014 Reacts violently with water.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
