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SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier Identification of the substance Sodium bromide ROTI®METIC 99,999 % (5N) Article number 5086 Registration number (REACH) It is not required to list the identified uses be- cause the substance is not subject to registration according to REACH (< 1 t/a). EC number 231-599- CAS number 7647-15- 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Laboratory chemical Laboratory and analytical use Uses advised against: (^) Do not use for products which come into contact with foodstuffs. Do not use for private purposes (household). 1.3 Details of the supplier of the safety data sheet Carl Roth GmbH + Co KG Schoemperlenstr. 3- D-76185 Karlsruhe Germany Telephone: +49 (0) 721 - 56 06 0 Telefax: +49 (0) 721 - 56 06 149 e-mail: [email protected] Website: www.carlroth.de Competent person responsible for the safety data sheet:
:Department Health, Safety and Environment e-mail (competent person): [email protected] 1.4 Emergency telephone number
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) This substance does not meet the criteria for classification in accordance with Regulation No 1272/ 2008/EC. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) not required
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086 Version: 2.0 en Replaces version of: 24.05. Version: (1)
date of compilation: 24.05. Revision: 16.11.
2.3 Other hazards Results of PBT and vPvB assessment According to the results of its assessment, this substance is not a PBT or a vPvB.
SECTION 3: Composition/information on ingredients
3.1 Substances Name of substance Sodium bromide Molecular formula NaBr Molar mass 102,9 g/mol CAS No 7647-15- EC No 231-599-
SECTION 4: First aid measures
4.1 Description of first aid measures
General notes Take off contaminated clothing. Following inhalation Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice. Following skin contact Rinse skin with water/shower. In all cases of doubt, or when symptoms persist, seek medical advice. Following eye contact Rinse cautiously with water for several minutes. In all cases of doubt, or when symptoms persist, seek medical advice. Following ingestion Rinse mouth. Call a doctor if you feel unwell. 4.2 Most important symptoms and effects, both acute and delayed Irritant effects, Vomiting, Spasms 4.3 Indication of any immediate medical attention and special treatment needed none
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086
SECTION 7: Handling and storage
7.1 Precautions for safe handling Avoid dust formation. Advice on general occupational hygiene Keep away from food, drink and animal feedingstuffs. 7.2 Conditions for safe storage, including any incompatibilities Store in a dry place. Keep container tightly closed. Incompatible substances or mixtures Observe hints for combined storage. Consideration of other advice: Ventilation requirements Use local and general ventilation. Specific designs for storage rooms or vessels Recommended storage temperature: 15 – 25 °C 7.3 Specific end use(s) No information available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters National limit values Occupational exposure limit values (Workplace Exposure Limits) This information is not available. Human health values Relevant DNELs and other threshold levels Endpoint Thresholdlevel route of exposureProtection goal, Used in Exposure time DNEL 4,75 mg/m³ human, inhalatory worker (industry) chronic - systemic effects DNEL 95 mg/kg bw/day human, dermal worker (industry) chronic - systemic effects DNEL 95 mg/kg bw/day human, dermal worker (industry) acute - systemic effects
Environmental values Relevant PNECs and other threshold levels
point^ End- Thresholdlevel Organism^ Environmental com-partment Exposure time PNEC 0,208 mg/l aquatic organisms water intermittent release PNEC 0,15 mg/l aquatic organisms freshwater short-term (single instance) PNEC 0,075 mg/l aquatic organisms marine water short-term (single instance)
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086
Relevant PNECs and other threshold levels
point^ End- Thresholdlevel Organism^ Environmental com-partment Exposure time PNEC 100 mg/l aquatic organisms sewage treatment plant(STP) short-term (single instance) PNEC 3,2 mg/kg terrestrial organisms soil short-term (single instance)
8.2 Exposure controls Individual protection measures (personal protective equipment) Eye/face protection
Use safety goggle with side protection. Skin protection
- hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. - type of material NBR (Nitrile rubber) - material thickness
0,11 mm - breakthrough times of the glove material 480 minutes (permeation: level 6) - other protection measures Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Respiratory protection
Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P1 (filters at least 80 % of airborne particles, colour code: White). Environmental exposure controls Keep away from drains, surface and ground water.
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086
SECTION 10: Stability and reactivity
10.1 Reactivity This material is not reactive under normal ambient conditions. 10.2 Chemical stability Hygroscopic solid. May cause decomposition by long-term light influence. 10.3 Possibility of hazardous reactions
Violent reaction with: Strong acid, Alkali metals, => Explosive properties 10.4 Conditions to avoid Direct light irradiation. 10.5 Incompatible materials There is no additional information. 10.6 Hazardous decomposition products Hazardous combustion products: see section 5.
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/ Classification according to GHS (1272/2008/EC, CLP) This substance does not meet the criteria for classification in accordance with Regulation No 1272/ 2008/EC. Acute toxicity Shall not be classified as acutely toxic. Acute toxicity Exposure route Endpoint Value Species Method Source oral LD50 4.200 mg/kg rat ECHA dermal LD50 >2.000 mg/kg rabbit ECHA Skin corrosion/irritation Shall not be classified as corrosive/irritant to skin. Serious eye damage/eye irritation Shall not be classified as seriously damaging to the eye or eye irritant. Respiratory or skin sensitisation Shall not be classified as a respiratory or skin sensitiser. Germ cell mutagenicity Shall not be classified as germ cell mutagenic. Carcinogenicity Shall not be classified as carcinogenic. Reproductive toxicity
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086
Shall not be classified as a reproductive toxicant. Specific target organ toxicity - single exposure Shall not be classified as a specific target organ toxicant (single exposure). Specific target organ toxicity - repeated exposure Shall not be classified as a specific target organ toxicant (repeated exposure). Aspiration hazard Shall not be classified as presenting an aspiration hazard. Symptoms related to the physical, chemical and toxicological characteristics
- If swallowed vomiting, Spasms - If in eyes Data are not available. - If inhaled Inhalation of dust may cause irritation of the respiratory system - If on skin Data are not available. - Other information none 11.2 Endocrine disrupting properties Not listed. 11.3 Information on other hazards There is no additional information.
SECTION 12: Ecological information
12.1 Toxicity Shall not be classified as hazardous to the aquatic environment. . Aquatic toxicity (acute) Endpoint Value Species Source Exposuretime LC50 >440 mg/l fish ECHA 96 h EC50 ≥1.000 mg/l aquatic invertebrates ECHA 48 h ErC50 >440 mg/l algae ECHA 72 h
Aquatic toxicity (chronic) Endpoint Value Species Source Exposuretime EC50 20,8 mg/l aquatic invertebrates ECHA 21 d
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086
There is no additional information. 14.7 Maritime transport in bulk according to IMO instruments The cargo is not intended to be carried in bulk.
14.8 Information for each of the UN Model Regulations Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional information Not subject to ADR, RID and ADN. International Maritime Dangerous Goods Code (IMDG) - Additional information Not subject to IMDG. International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information Not subject to ICAO-IATA.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Relevant provisions of the European Union (EU) Restrictions according to REACH, Annex XVII not listed List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list Not listed. Seveso Directive 2012/18/EU (Seveso III) No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap-plication of lower and upper-tier re- quirements
Notes
not assigned Deco-Paint Directive VOC content 0 % , 0 g/l Industrial Emissions Directive (IED) VOC content 0 % VOC content 0 g/l Directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment (RoHS) not listed Regulation concerning the establishment of a European Pollutant Release and Transfer Register (PRTR) not listed
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086
Water Framework Directive (WFD) List of pollutants (WFD) Name of substance Name acc. to inventory CAS No Listed in Remarks Sodium bromide Metals and their compounds A) Legend A) Indicative list of the main pollutants Regulation on the marketing and use of explosives precursors not listed Regulation on drug precursors not listed Regulation on substances that deplete the ozone layer (ODS) not listed Regulation concerning the export and import of hazardous chemicals (PIC) not listed Regulation on persistent organic pollutants (POP) not listed Other information Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un- der the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers. National inventories Country Inventory Status AU AICS substance is listed CA DSL substance is listed CN IECSC substance is listed EU ECSI substance is listed EU REACH Reg. substance is listed JP CSCL-ENCS substance is listed KR KECI substance is listed MX INSQ substance is listed NZ NZIoC substance is listed PH PICCS substance is listed TR CICR substance is listed TW TCSI substance is listed US TSCA substance is listed Legend AICSCICR Australian Inventory of Chemical SubstancesChemical Inventory and Control Regulation CSCL-ENCSDSL List of Existing and New Chemical Substances (CSCL-ENCS)Domestic Substances List (DSL) ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086
Abbr. Descriptions of used abbreviations GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-tions IATA International Air Transport Association IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA) ICAO International Civil Aviation Organization IMDG International Maritime Dangerous Goods Code LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %lethality during a specified time interval LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during aspecified time interval NLP No-Longer Polymer PBT Persistent, Bioaccumulative and Toxic PNEC Predicted No-Effect Concentration REACH Registration, Evaluation, Authorisation and Restriction of Chemicals RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-tions concerning the International carriage of Dangerous goods by Rail) SVHC Substance of Very High Concern VOC Volatile Organic Compounds vPvB Very Persistent and very Bioaccumulative Key literature references and sources for data Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures. Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU. Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Mari- time Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA). Disclaimer This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.
Sheet format according to Regulation (EC) No. 1907/
(REACH)
Sodium bromide ROTI®METIC 99,999 % (5N)
article number: 5086
