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Stronger intermolecular forces between molecules make it more difficult for those molecules to be pulled apart. Therefore, stronger intermolecular forces result ...
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Chapter 10 Practice Worksheet: Liquids, Solids, and Phase Changes
a. CH 3 Cl b. CH 4 c. CCl 4 d. SO 2 e. CO 2 f. H 2 O
g. NH 3 h. CH 3 –CH 3 i. CH 2 =CH 2 j. CH 3 OH k. CH 3 NH 2
a. Ion-dipole: _attractive forces between an ion and a polar molecule _____
b. Dipole-dipole: attractive forces between polar molecules (pure substance or mixture)__
c. London dispersion forces: _attractive forces between all molecules (induced dipoles uneven electron distribution _ d. Hydrogen bonding: _ attractive forces between hydrogen and nitrogen, oxygen, or fluorine __
CH 3 Cl __London, dipole-dipole ________________________________________ H 2 _ London _________________________________________ HCl __London, dipole-dipole ________________________________________ Ne __ London ________________________________________ NH 3 ___London, dipole-dipole, hydrogen _______________________________________ HF __London, dipole-dipole, hydrogen ________________________________________ CH 3 OH __London, dipole-dipole, hydrogen ________________________________________ C 2 H 4 ___ London _______________________________________ CO 2 ___ London _______________________________________ CO ___London, dipole-dipole _______________________________________
In order for an ionic solid to dissolve, there is competition between the ion-ion forces within the compound and ion-dipole forces between ions and water molecules. If the ion-dipole forces are stronger, the solid will dissolve in water.
Stronger intermolecular forces between molecules make it more difficult for those molecules to be pulled apart. Therefore, stronger intermolecular forces result in higher boiling points.
Surface tension is the resistance of a liquid to spread out. Viscosity is a measure of a substance’s resistance to flow. As the strength of IMF’s increase, surface tension and viscosity increase. Molecules are more strongly attracted to each other and will be less likely to spread apart or to flow.
H 2 < Ne < CO 2 < CO < HF < BaCl 2
Heats of vaporization define the boiling point and heats of fusion define the melting point of a substance. Melting requires considerably less energy than boiling because IMF’s do not need to be completely overcome. In order for a substance to boil, molecules must go into the gas phase which requires that there are no IMF’s acting on the molecules (IMF’s completely broken).
Normal boiling and melting points occur at 1 atm of pressure.