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Answer key pdf for chemistry coordination compounds
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(d) 1 mole of AgNO 3 precipitates one free chloride ion (CI-). Here, 3 moles of AgCl are precipitated by excess of AgNO 3. Hence, there must be three free Cl-^ ions. So, the formula of the complex can be [Cr(H 2 O) 6 ]Cl 3 and correct choice is (d).
(b) Here, out of given four options standards reduction potential of chromium has highest negative value hence most powerful reducing agent is chromium.