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Cordinatton lompsunds
" Metal^ atons^ oonol^ to^ o.^
et amiens/ettae
meleees ly sehOing electen.
Ca.Chehohyee- agneium
Haemogotin en
Vt.B2 - Cobalt
henel teyi
Centrae Metol io: euis oacial
(eacceptor
2igamds: leis base (e
Gma olona)
be &moee
eem nachomnolecues/protuns)moleuules,^ org^ ens a
DentictyiNo.ate pair^ olonated by egonol
a)monoolentote : single olono ton
b
idetute :Tuso oono
atoms
coNea
C, Polydentale Beae doer atems.
"Hegadette (6): [EDTA"J
#di-|or
poly-dletate ligands wnng
2me dens
atoimltameusy ch¿iata ligomd
.
Achelate bonpwndy ene
gtotte than un oeutt
compaundpnd m
rmbidentate eigomals-
ning
denostom t^ at^ one thhetwooiyteent omly
cne olonater
NO’oygem /Nitoogn
ScN’suajitregenbe
3-Coordinatnhee4. Coardinatiemholyhedron: : CMI+ igamdyhatialamgemet
Coerdinatin o.^ :No.ot ligond
to whic hetl eovoutems,
bonded.
oxidotieno. ot CMI: Chae t would cary
all eigamas
Homoleptic/ Mettrolate
ligand
NO chelating^ tung Dentiuty "Dentieity : CN. 8- Cernlen inCoohclinatin HAgegote es^ metalion^
hth
(ondinatin re
CMI
Nonendatwe:
" ligamdsoenmed alpiaticag "e, neutral^ conmsln^ in^ Named^ as^ it^ ç
fe
[u(NH3)u]t So
" Potitue pat is named^ tist^ in^ acmlencomhemd^ /
Neute N-Amnmin,o- Auay NO-Nitreyl, PH3- Phospiune
Mn
ini-Fuso euico, o°Grido ,s-sup
Ceso Ng- Arido, - Nitiolo, ydidó
Cotoric ]0, - (^) erygenim, No- (^) itrylim, (^) No,-Niteni (Ntoreinn)
when (^) cenen ion is chin
Denti
Lead
4(Maj be
Mangomee
chsemals Frate Arvgentae
a
plumoale
mangmale
not he
wenes Theey Aea wene(wis^ chemist)^ insto mtrctue ot^ cooraunat^
toeas
Prinany valeny
"Satistied byeustaies
lonisalle
" lant pedit
geometng
Beconalag valemd
.ce
"(oonaon
"Aatistied ry^ (-e)^ utel
seeies. " Non iosale " (^) Predrct the (^) geochg
eumtal esidence W.T
inita'ony otVeT: i) tydeesm^ t
giecolo/enlannit.
oynamic taties V)Nopeediten^
Aegardng tetrohehal flo
stuetuhes ioen't distngth e7w^ wpL'&^
SFL
ystal Reld Theti " tlectratotic^ ymoolel^ cenhdering igand 96 nutral malels.
BARC TERMS :
field
egenerted d'oiblsin M
Aegenente (J'tul i
dyz
egset +o.6do
t2set +o.4b
factohs aGtetng cE
X= o. em tg
n octehedhal tield
tag
te
CFSE -0-
ceSE=- 0.
kFSE -1.2do
field CoN=6)
Iwoes ma asunmphns
VI. ab:
6
SFL(aim
SFL
SFL
CESE -0-6,
3
wFL
jCFse z^ -0.
VIl]. d&
2
cSE
WFL
CESE= -0.8 Ao
TCFSE =o
Qs, 1tooms
"for (^) mymneial (^) bidentte (^) ligands:
CHNMZ P
[Mu:
co
NO
khuee eo atom
(fac
at
NN
Tray
Mz
.NM2-cn
Tsans
scthod
&. ophtal Komeikm?
Two to
ophial actieasai enantom
CChia]
ag,camtbe eum i) Deetro (d) (Rotte to
dhulat
3+
detro
8kouetwy
enisoton syo
some (^) nelecula Gamwla, (^) dibteht Suingieny stuctuhe
(Rotute to eett)
’ (^) CMI (^) has (^) olitt
lnage th amident ate lig an.
3.CooidinenYelawitte-N-NO) s6:
3+
itite-ofOND)
en
bl.‘
C-0 be
Rule:
(Chae n deity i metal
nAnt binohy
benane:"M-Cboe
ueto
e >ymdskja T-acid lignd,
y this scttectya ymee ðect s
s
Cabentoacat tal
d-onbftal
Metal
MO- Co
Bonunan meal aenye
Mn (0)’ dsp^ TB.p
Ni (C0)4^ thod’p
Metal
Cangnad
i) Ferome b)r bomded!
a) banabonded:oblw MeuC
tTyees covoletD.c:
arent bond blwM ec:
Q o.CCovalent
enic bona bjuhusent metal &car.
) onic 0.C
ypes
- C9dunaton
ponhën someind
