taula pka, Apuntes de Bioquímica

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Appendices 1261 APPENDIX 5 pK, Values for Represent: Compounds Compound pK, Compound pK, Compound pK, CH,C=XÑH -10.1 Y 10 Í 43 HI -10 ON NHs Ñ cu) con > HBr 3 O Lo o +0H e : [ I l 45 y» N CH50: COH CH,CH 3 Ao Ñ 07 +0H Il , 1 CI,CHCOH 13 (ya , 46 CH,CCH, 23 11S0; 20 me] Hal, HPO, 21 2? CH ÓH, 68 ay > CH¿COH 48 05 K) Y ? - Sy CH,COCH, 65 GH 49 +0OH CH,¿COH -6.1 N + (0) 5.1 H)SO, S Il + CICH,COH 2.8 CH; NH) Sy l Il FCH,COH 2.7 Qu 38 o N 0 52 HH BICH,COH 29 H o Y CH¿CH¿0CH,CH; — -3.6 1 Ñ $3 H ICH,COH 3.2 cuo—L Js CH¿CH,QH -24 HE 3.2 ñ H HNO) 3.4 CH; NHCH, 5.5 CH¿QH -2.5 2 CH, Ho -1.7 on )-con 3.4 2 0 HNO, -13 o CH¿CCH,CH 59 CH¿SO¿H -12 ll Ñ 350y HCOH 38 HONH; 6.0 e som 060 . H,COy 64 a 9H HN NH (o) CH¿CNH> 0.0 Í HS 7.0 Br COH 40 lo) 1 7.1 F,CCOH 02 o 02N OH 1 (Ey con 42 CI¿CCOH 0.64 : H>POz 7.2 Py 7.8 N—OH 0.79 SH 1262 Appendices APPENDIX 5 pK, Values for Representative Compounds Compound pk, Compound pK, Compound PK, N 80 NH. 107 Y WA ¡ a : CH,CH ul H E uo Ñan 107 (CHCOH 18 H>,NNH; 8.1 (CH3NHa : o CH;CH¿NH, 10.7 CH,CCH, 20 CH¿COOH 82 0 CH,CHNO) 86 O ma CH,COEt 24,5 2 $ NX HC=CH 25 CH,CCH,CCH, 89 HH CH,C=N 25 NOYyN Lo) 113 ¡ TS 89 WN Il NY ¿On CH3CN(CH)2 30 HC= 9.1 HPO3" 123 NH; 36 O CF¿CH¿0H 2.4 Ly 36 N IN 93 7 $ H Ho EtOCCH¿COEt-=—— 133 CH¿NH, 40 HC=CCH,0H 13.5 aL) on 9.4 (Oye 41 X NH, 94 H,NCNH) 13.7 O) a CH; HOCH,CH_NH, 9.5 $ CHNCH.CHOH 139 CH,=CHCH, 43 ll CH,= HNCH,CO- 98 45 m4 NoNH 14.4 V 46 (Oy on 10.0 a CH, 50 OS 155 CHCHs 50 cu) om 10.2 ? 157 CH,CH,OH 15.9 HCO; 102 o CH¿NO, 10.2 CH¿CNH) 16 0 HN . Il 2 Ly) 105 (yo 16.0 CH¿CH,SH 10.5 + / -17 (CHy)¿NH 10.6 ( N y gl E CH¿CCH,COEt 10.7 CH¿NH, 10.7