Propriedades críticas | Notas de aula Termodinâmica Aplicada

►

639

APPENDIX A

Physical Property Data

► A.1 CRITICAL CONSTANTS, ACENTRIC FACTORS, AND ANTOINE COEFFICIENTS:1

The Antoine equation is of the form: ln1Psat 3bar 4 2 5A2

T3K41C

TABLE A.1.1 Organic compounds

Formula Name MW3

/mol4 Tc 3K4Pc 3bar4

A B C T

Formaldehyde 30.026 408 65.86 0.253 9.8573 2204.13 230.1

185 271

H4Methane 16.042 190.6 46.00 0.008 8.6041 897.84 27.16 93 120

Methanol 32.042 512.6 80.96 0.559 11.9673 3626.55 234.29 257 364

2H4Acetylene 26.038 308.3 61.40 0.184 9.7279 1637.14 219.77 194 202

2H3

Acetonitrile 41.052 548 48.33 0.321 9.6672 2945.47 249.1

260 390

2H4Ethylene 28.053 282.4 50.36 0.085 8.9166 1347.01 218.1

120 182

2H4

Acetaldehyde 44.053 461 55.73 0.303 9.6279 2465.15 237.15 210 320

2H4

Ethylene oxide 44.053 469 71.94 0.200 10.1198 2567.61 229.01 300 310

2H4

2Acetic acid 60.052 594.4 57.86 0.454 10.1878 3405.57 2

6.34 290 430

2H6Ethane 30.069 305.4 48.74 0.099 9.0435 1511.42 217.16 130 199

2H6

Ethanol 46.068 516.2 63.83 0.635 12.2917 3803.98 241.68 270 369

3H6Propylene 42.080 365.0 46.20 0.148 9.0825 1807.53 226.1

160 240

3H6

Acetone 58.079 508.1 47.01 0.309 10.0311 2940.46 23

.93 241 350

3H8Propane 44.096 370.0 42.44 0.152 9.1058 1872.46 22

.16 164 249

3H8

1-Propanol 60.095 536.7 51.68 0.624 10.9237 3166.38 280.1

285 400

4H61,3-Butadiene 54.090 425 43.27 0.195 9.1525 2142.66 234.30 215 290

4H8cis-2-Butene 56.106 435.6 42.05 0.202 9.1969 2210.71 236.1

200 305

4H8trans-2-Butene 56.106 428.6 41.04 0.214 9.1975 2212.32 233.1

200 300

4H8

2Ethyl acetate 88.105 523.2 38.30 0.363 9.5314 2790.50 257.15 260 385

4H10 n-Butane 58.122 425.2 37.90 0.193 9.0580 2154.90 234.42 195 290

4H10 Isobutane 58.122 408.1 36.48 0.176 8.9179 2032.76 233.1

187 280

4H10

n-Butanol 74.122 562.9 44.18 0.590 10.5958 3137.02 294.43 288 404

5H10 1-Pentene 70.133 464.7 40.53 0.245 9.1444 2405.96 239.63 220 325

5H12 n-Pentane 72.149 469.6 33.74 0.251 9.2131 2477.07 239.94 220 330

6H6Benzene 78.112 562.1 48.94 0.212 9.2806 2788.51 2

2.36 280 377

6H6

Phenol 94.111 694.2 61.30 0.440 9.8077 3490.89 298.

9 345 481

6H7

Aniline 93.127 699 53.09 0.382 10.0546 3857.52 273.15 340 500

6H12 Cyclohexane 84.159 553.4 40.73 0.213 9.1325 2766.63 2

0 280 380

6H12 1-Hexene 84.159 504.0 31.71 0.285 9.1887 2654.81 247.30 240 360

6H14 n-Hexane 86.175 507.4 29.69 0.296 9.2164 2697.55 248.78 245 370

(Continued)

1 For a more complete set of compounds, consult ThermoSolver, the text software.

Pré-visualização parcial do texto

Baixe Propriedades críticas e outras Notas de aula em PDF para Termodinâmica Aplicada, somente na Docsity!

APPENDIX A

B

T 3 K 4 1 C

TABLE A.1.1 Organic compounds

( Continued )

640 ► Appendix A Physical Property Data

TABLE A.1.1 Continued TABLE A.1.2 Inorganic Compounds

► A.1 CRITICAL CONSTANTS, ACENTRIC FACTORS, AND ANTOINE COEFFICIENTS: Physical Property Data - The Antoine equation is of the form: ln 1 P sat^3 bar4 2^5 A
- CH 2 O Formaldehyde 30.026 408 65.86 0.253 9.8573 2204.13 2 30.1 Formula Name MW 3 g/mol 4 Tc 3 K 4 Pc 3 bar 4 v A B C T min T mix
- CH 4 Methane 16.042 190.6 46.00 0.008 8.6041 897.84 2 7.16
- CH 4 O Methanol 32.042 512.6 80.96 0.559 11.9673 3626.55 2 34.29
- C 2 H 4 Acetylene 26.038 308.3 61.40 0.184 9.7279 1637.14 2 19.77
- C 2 H 3 N Acetonitrile 41.052 548 48.33 0.321 9.6672 2945.47 2 49.1
- C 2 H 4 Ethylene 28.053 282.4 50.36 0.085 8.9166 1347.01 2 18.1
- C 2 H 4 O Acetaldehyde 44.053 461 55.73 0.303 9.6279 2465.15 2 37.15
- C 2 H 4 O Ethylene oxide 44.053 469 71.94 0.200 10.1198 2567.61 2 29.01
- C 2 H 4 O 2 Acetic acid 60.052 594.4 57.86 0.454 10.1878 3405.57 25 6.34
- C 2 H 6 Ethane 30.069 305.4 48.74 0.099 9.0435 1511.42 2 17.16
- C 2 H 6 O Ethanol 46.068 516.2 63.83 0.635 12.2917 3803.98 2 41.68
- C 3 H 6 Propylene 42.080 365.0 46.20 0.148 9.0825 1807.53 2 26.1
- C 3 H 6 O Acetone 58.079 508.1 47.01 0.309 10.0311 2940.46 235 .93
- C 3 H 8 Propane 44.096 370.0 42.44 0.152 9.1058 1872.46 225 .16
- C 3 H 8 O 1-Propanol 60.095 536.7 51.68 0.624 10.9237 3166.38 2 80.1
- C 4 H 6 1,3-Butadiene 54.090 425 43.27 0.195 9.1525 2142.66 2 34.30
- C 4 H 8 cis -2-Butene 56.106 435.6 42.05 0.202 9.1969 2210.71 2 36.1
- C 4 H 8 trans -2-Butene 56.106 428.6 41.04 0.214 9.1975 2212.32 2 33.1
- C 4 H 8 O 2 Ethyl acetate 88.105 523.2 38.30 0.363 9.5314 2790.50 2 57.15
- C 4 H 10 n -Butane 58.122 425.2 37.90 0.193 9.0580 2154.90 2 34.42
- C 4 H 10 Isobutane 58.122 408.1 36.48 0.176 8.9179 2032.76 2 33.1
- C 4 H 10 O n -Butanol 74.122 562.9 44.18 0.590 10.5958 3137.02 2 94.43
- C 5 H 10 1-Pentene 70.133 464.7 40.53 0.245 9.1444 2405.96 2 39.63
- C 5 H 12 n -Pentane 72.149 469.6 33.74 0.251 9.2131 2477.07 2 39.94
- C 6 H 6 Benzene 78.112 562.1 48.94 0.212 9.2806 2788.51 25 2.36
- C 6 H 6 O Phenol 94.111 694.2 61.30 0.440 9.8077 3490.89 2 98.
- C 6 H 7 N Aniline 93.127 699 53.09 0.382 10.0546 3857.52 2 73.15
- C 6 H 12 Cyclohexane 84.159 553.4 40.73 0.213 9.1325 2766.63 25 0.
- C 6 H 12 1-Hexene 84.159 504.0 31.71 0.285 9.1887 2654.81 2 47.30
- C 6 H 14 n -Hexane 86.175 507.4 29.69 0.296 9.2164 2697.55 2 48.78
C 7 H 8 Toluene 92.138 591.7 41.14 0.257 9.3935 3096.52 2 53.67 Formula Name MW 3 g/mol 4 Tc 3 K 4 Pc 3 bar 4 v A B C T min T max
C 7 H 14 1-Heptene 98.186 537.2 28.37 0.358 9.2692 2895.51 2 53.97
C 7 H 16 n -Heptane 100.202 540.2 27.36 0.351 9.2535 2911.32 25 6.
C 8 H 8 Styrene 104.149 647.0 39.92 0.257 9.3991 3328.57 2 63.72
C 8 H 10 o -Xylene 106.165 630.2 37.29 0.314 9.4954 3395.57 25 9.46
C 8 H 10 m -Xylene 106.165 617.0 35.46 0.331 9.5188 3366.99 25 8.04
C 8 H 10 p -Xylene 106.165 616.2 35.16 0.324 9.4761 3346.65 2 57.84
C 8 H 10 Ethylbenzene 106.165 617.1 36.07 0.301 9.3993 3279.47 25 9.9
C 8 H 16 1-Octene 112.213 566.6 26.24 0.386 9.3428 3116.52 2 60.39
C 8 H 18 n -Octane 114.229 568.8 24.82 0.394 9.3224 3120.29 2 63.63
C 9 H 20 n -Nonane 128.255 594.6 23.10 0.444 9.3469 3291.45 2 71.33
C 10 H 8 Naphthalene 128.171 748.4 40.53 0.302 9.5224 3992.01 2 71.29
C 10 H 22 n -Decane 142.282 617.6 21.08 0.490 9.3912 3456.80 2 78.67
Ar Argon 39.948 150.8 48.74 2 0.004 8.6128 700.51 25 .84 Formula Name MW 3 g/mol 4 Tc 3 K 4 Pc 3 bar 4 v A B C T min T max
BCl 3 Boron trichloride 117.169 451.95 38.71 0.148 9.0985 2242.71 2 38.99
B 2 H 6 Diborane 27.670 289.80 40.50 0.138 8.7074 1377.84 2 22.18
Br 2 Bromine 159.808 584 103.35 0.132 9.2239 2582.32 25 1.
CCl 3 F Trichlorofluoromethane 137.367 471.2 44.08 0.188 9.2314 2401.61 2 36.3
CF 4 Carbon tetrafluoride 88.004 227.6 37.39 0.191 9.4341 1244.55 2 13.06
C 2 F 6 Hexafluoroethane 138.012 292.8 30.42 0.255 9.1646 1559.11 2 24.
CHCl 3 Chloroform 119.377 536.4 54.72 0.216 9.3530 2696.79 2 46.16
CO Carbon monoxide 28.010 132.9 34.96 0.049 7.7484 530.22 2 13.1
CO 2 Carbon dioxide 44.010 304.2 73.76 0.225 15.9696 3103.39 2 0.16
CS 2 Carbon disulfide 76.143 552 79.03 0.115 9.3642 2690.85 2 31.62
Cl 2 Chlorine 70.905 417 77.01 0.073 9.3408 1978.32 2 27.01
F 2 Fluorine 37.997 144.3 52.18 0.048 9.0498 714.10 2 6.00
H 2 Hydrogen 2.016 33.2 12.97 2 0.22 7.0131 164.90 3.19
HBr Hydrogen bromide 80.912 363.2 85.52 0.063 7.8485 1242.53 2 47.86
HCN Hydrogen cyanide 27.025 456.8 53.90 0.407 9.8936 2585.80 2 37.15
HCl Hydrogen chloride 36.461 324.6 83.09 0.12 9.8838 1714.25 2 14.4
H 2 O Water 18.015 647.3 220.48 0.344 11.6834 3816.44 2 46.13
H 2 S Hydrogen sulfide 34.082 373.2 89.37 0.100 9.4838 1768.69 2 26.06
NH 3 Ammonia 17.031 405.6 112.77 0.250 10.3279 2132.50 2 32.98
He Helium-4 4.003 5.19 2.27 2 0.387 5.6312 33.7329 1.79 3.7 4.
HF Hydrogen fluoride 20.006 461 64.85 0.372 11.0756 3404.49 15.06
Kr Krypton 83.800 209.4 55.02 2 0.002 8.6475 958.75 2 8.71
N 2 Nitrogen 28.013 126.2 33.84 0.039 8.3340 588.72 2 6.60
NF 3 Nitrogen trifluoride 71.002 234 45.29 0.132 8.9905 1155.69 2 15.37
N 2 O Nitrous oxide 44.013 309.6 72.45 0.160 9.5069 1506.49 225 .99
NO Nitric oxide 30.006 180 64.85 0.607 13.5112 1572.52 2 4.88
NO 2 Nitrogen dioxide 46.006 431.4 101.33 0.86 13.9122 4141.29 3.65
Ne Neon 20.180 44.4 27.56 0.00 7.3897 180.47 2 2.61
O 2 Oxygen 31.999 154.6 50.46 0.021 8.7873 734.55 2 6.4
PH 3 Phosphene 33.998 324.45 65.35 0.042 9.2700 1617.91 2 11.07
SF 6 Sulfur hexafluoride 146.056 318.7 37.59 0.286 12.7583 2524.78 2 11.16
SO 2 Sulfur dioxide 64.065 430.8 78.83 0.251 10.1478 2302.35 2 35.97

Propriedades críticas, Notas de aula de Termodinâmica Aplicada

Documentos relacionados

Pré-visualização parcial do texto

Baixe Propriedades críticas e outras Notas de aula em PDF para Termodinâmica Aplicada, somente na Docsity!

B

T 3 K 4 1 C

640 ► Appendix A Physical Property Data